زمین‌شناسی، سنگ‌نگاری، کانی‌شناسی مدرن و بررسی تشکیل کانی‌ها و کانه‌های ذخیره مس (-طلا) قره تپه (شرق ماکو، شمالغرب ایران)

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه علوم زمین، دانشکده علوم طبیعی، دانشگاه تبریز، تبریز، آذربایجان شرقی، ایران

2 گروه گوهرشناسی، پژوهشکده زمین‌شناسی پزشکی و محیط‌زیست، دانشگاه تبریز، تبریز، آذربایجان شرقی، ایران

10.22128/ijcm.2025.3078.1013

چکیده

منطقه معدنی قره‌تپه در شرق ماکو از سنگ‌های کربناتی پرمین با دولومیت‌های غنی از مواد آلی و واحدهای تبخیری تشکیل شده است. کانه‌زایی مس به‌صورت‌های رگه‌-رگچه‌ای شامل کالکوسیت، کوولیت، پیریت و کالکوپیریت رخ داده و اکسایش آنها منجر به تشکیل مالاکیت، آزوریت و گوتیت شده است. سیل‌های میکرودیوریتی منبع احتمالی مس و گسل‌ها مسیر اصلی مهاجرت سیال­ها هستند. داده‌های پراش پرتوی ایکس (XRD)، طیف­سنجی تبدلی فوریه فروسرخ (FTIR) و میکروسکوپ الکترونی روبشی (SEM) بیانگر کانه‌زایی چندمرحله‌ای و روزادی هستند؛ کانی‌های اصلی کالکوسیت و دولومیت با همراهی پیریت، هماتیت و کوارتز، اثر چند رویداد گرمابی با ترکیب‌های متفاوت را نشان می‌دهند. تغییرهای ساختاری دولومیت بسته به شدت دگرسانی تأیید شده و طلا به‌صورت پراکنده در دولومیت و در ارتباط با سولفیدهای مس شناسایی شده است. در مجموع، سنگ دولومیت میزبان و کنترل‌کننده اصلی سیال ها بوده و کانه‌زایی مس–طلا در اثر جنس سنگ، ساختارهای گسلی و فعالیت گرمابی شکل گرفته و پتانسیل اکتشافی بالایی دارد.

کلیدواژه‌ها


عنوان مقاله [English]

Geology, Petrography, Modern Mineralogy, and Formation of Minerals and Ore Minerals of the Qareh Tappeh Cu (–Au) Deposit (East of Maku, Northwestern Iran)

نویسندگان [English]

  • Mohamad Reza Hosseinzadeh 1 2
  • Ali Asadi 1 2
  • Yalda Vahed 1
  • Vartan Simmonds 1
1 Department of Earth Sciences, Faculty of Natural Sciences, University of Tabriz, Tabriz, Iran
2 Gemology Group, Research Institute of Medical and Environmental Geology, University of Tabriz, Tabriz, East Azerbaijan, Iran
چکیده [English]

The Qareh Tappeh mineralized zone, situated east of Maku, consists of Permian carbonate rocks that include organic-rich dolomites and evaporite layers. Copper occurs in veins and veinlets, primarily as chalcocite, covellite, pyrite, and chalcopyrite, with oxidation producing secondary minerals such as malachite, azurite, and goethite. Microdioritic sills are suggested as a potential copper source, while faults have served as principal conduits for hydrothermal fluids. Analyses using XRD, FTIR, and SEM reveal multiphase, epigenetic mineralization; chalcocite and dolomite dominate, accompanied by pyrite, hematite, and quartz, reflecting multiple hydrothermal events with varied fluid compositions. Structural changes in dolomite correlate with the intensity of alteration, and fine gold disseminations occur within dolomite and alongside copper sulfides. Overall, dolomite acted both as the host rock and as the main geochemical regulator of mineralizing fluids. The Cu–Au mineralization was governed by lithology, fault systems, and hydrothermal processes, highlighting the area’s significant exploration potential.

کلیدواژه‌ها [English]

  • Copper (Gold) mineralization
  • hydrothermal fluids
  • dolomite
  • X-ray diffraction
  • electron microscopy
  • Maku
[1] Hitzman M.W., Selley D., Bull S., "Formation of sedimentary rock-hosted stratiform copper deposits through Earth history", Economic Geology 105 (2010) 627–639. https://doi.org/10.2113/gsecongeo.105.3.627
[2] Sillitoe R.H., "Copper provinces", in: Hedenquist J.W., Harris M., Camus F. (Eds.), Geology and genesis of major copper deposits and districts of the world: a tribute to Richard H. Sillitoe, SEG Special Publication 16 (2012) 1–18.
[3] Large R., Bull S., McGoldrick P., Walters S., Derrick G.M., Carr G.R., "Stratiform and strata-bound Zn-Pb-Ag deposits in Proterozoic sedimentary basins, Northern Australia", Economic Geology 100 (2005). https://hdl.handle.net/102.100.100/494032
[4] Soliman M.F., El Goresy A., "Framboidal and idiomorphic pyrite in the upper Maastrichtian sedimentary rocks at Gabal Oweina, Nile Valley, Egypt: Formation processes, oxidation products and genetic implications to the origin of framboidal pyrite", Geochimica et Cosmochimica Acta 90 (2012) 195–220. https://doi.org/10.1016/j.gca.2012.05.004
[5] Borg G., "It’s all about timing – the origin of the European Kupferschiefer ores", World of Mining – Surface and Underground 69 (2017) 24–30.
[6] Cabral A.R., Beaudoin G., Taylor B.E., "The Transfiguration continental red-bed Cu–Pb–Zn–Ag deposit, Quebec Appalachians, Canada", Mineralium Deposita 44 (2009) 285–301. https://doi.org/10.1007/s00126-008-0217-z
[7] Cox D.P., Lindsey D.A., Singer D.A., Moring B.C., Diggles M.F., "Sediment-hosted copper deposits of the world: Deposit models and database", U.S. Geological Survey Open-File Report 2003-107 (2003). https://doi.org/10.3133/ofr2003107
[8] Brown A.C., "Low-temperature sediment-hosted copper deposits", in: Holland H.D., Turekian K.K. (Eds.), Treatise on Geochemistry, 2nd ed., Vol. 13, Elsevier (2014) 251–271. https://doi.org/10.1016/B978-0-08-095975-7.01110-4
[9] Maghfouri S., Rastad E., Borg G., Hosseinzadeh M.R., Movahednia M., Mahdavi A., Mousivand F., "Metallogeny and temporal–spatial distribution of sediment-hosted stratabound copper (SSC-type) deposits in Iran; implications for future exploration", Ore Geology Reviews 127 (2020) 103834. https://doi.org/10.1016/j.oregeorev.2020.103834
[10] Dare F., "The Study of Geology, Mineralogy and Geochemistry of Ghareh-Tappeh Copper Index (Maku- West Azerbaijan)", Unpublished M.Sc. Thesis, University of Tabriz, Iran (2015) 122 pp. (in Persian with English abstract).
[11] Aminazar R., Abbasi S., "1:100000 geological sheet of Maku", Geological Survey of Iran (2003).
[12] Ramezani J., Tucker R.D., "The Saghand Region, Central Iran: U-Pb geochronology, petrogenesis and implications for Gondwana tectonics", American Journal of Science 303 (2003) 622–665. https://doi.org/10.2475/ajs.303.7.622
[13] Berberian M., King G.C.P., "Towards a paleogeography and tectonic evolution of Iran", Canadian Journal of Earth Sciences 18 (1981) 210–265. https://doi.org/10.1139/e81-019
[14] Stocklin J., "Structural History and Tectonic of Iran: A Review", American Association of Petroleum Geologists Bulletin 52 (1968) 1229–1258.
[15] Stocklin J, Nabavi MH. ,“Tectonic Map of Iran 1:2,500,000”, Geological Survey of Iran; 1973.
[16] Shafaii Moghadam H., Corfu F., Stern R.J., Lotfi Bakhsh A., "The Eastern Khoy metamorphic complex of NW Iran: a Jurassic ophiolite or continuation of the Sanandaj–Sirjan Zone?", Journal of the Geological Society 176 (2019) 517–529. doi:10.1144/jgs2018-081.
[17] Ghasemi Siani M., Lentz D.R., Nazarian M., "Geochemistry of igneous rocks associated with mineral deposits in the Tarom-Hashtjin metallogenic province, NW Iran: An analysis of the controls on epithermal and related porphyry-style mineralization", Ore Geology Reviews 126 (2020) 103753. doi:10.1016/j.oregeorev.2020.103753.
[18] Alavi M., "Tectonics of the Zagros orogenic belt of Iran: New data and interpretations", Tectonophysics 229 (1994) 211–238. https://doi.org/10.1016/0040-1951(94)90030-2
[19] Rajabpour S., Abedini A., Alipour S., Lehmann B., Jiang S.-Y., "Geology and geochemistry of the sediment-hosted Cheshmeh-Konan redbed-type copper deposit, NW Iran", Ore Geology Reviews 86 (2017) 154–171. https://doi.org/10.1016/j.oregeorev.2017.02.013
[20] Klein C., Hurlbut J., “Manual of Mineralogy”, John Wiley and Sons, New York (1993) 596.
[21] Cullity B.D., “Elements of X-ray Diffraction”, Addison-Wesley Publishing Company, Inc. (1956).
[22] Rietveld H.M., "A profile refinement method for nuclear and magnetic structures", Journal of Applied Crystallography 2 (1969) 65–71. https://doi.org/10.1107/S0021889869006558
[23] Scherrer P., "Bestimmung der inneren Struktur und der Größe von Kolloidteilchen mittels Röntgenstrahlen", in: Kolloidchemie: Ein Lehrbuch. Chemische Technologie in Einzeldarstellungen, Springer, Berlin, Heidelberg (1912). https://doi.org/10.1007/978-3-662-33915-2_7
[24] Harris D.C., “Quantitative Chemical Analysis”, 8th ed., W.H. Freeman (2010).
[25] Smith B.C., “Infrared Spectral Interpretation: A Systematic Approach”, 1st ed., CRC Press (1999). https://doi.org/10.1201/9780203750841
[26] Whitney D.L., Evans B.W., “Abbreviations for names of rock-forming minerals”, Am Mineral. (2010);95(1):185–187. doi: 10.2138/am.2010.3371
[27] Gruszecka-Kosowska A., Wdowin M., Kosowski T., Klimek A., "An analysis of the chemistry, mineralogy and texture of waste dolomite powder used to identify its potential application in industry", Geology, Geophysics and Environment 41 (2016) 343–356. https://doi.org/10.7494/geol.2015.41.4.343
[28] Roshanfar M., Farahani Z., Khanlarian M., et al., “Phytoextraction of copper from copper waste rock by Tagetes sp”, Environ Sci Pollut Res. (2024);31:1026–1032. doi: 10.1007/s11356-023-31199-9
[29] Yu K., Qiu L., Cao Y., Sun P., Qu C., Yang Y., "Hydrothermal origin of early Permian saddle dolomites in the Junggar Basin, NW China", Journal of Asian Earth Sciences 184 (2019) 103990. https://doi.org/10.1016/j.jseaes.2019.103990.
[30] Guilbert J.M., Park C.F., “The Geology of Ore Deposits”, W.H. Freeman and Company, New York (1986).
[31] Loeblich A.R., Tappan H., “Foraminiferal Genera and Their Classification”, 1st ed., Springer, New York (1988). https://doi.org/10.1007/978-1-4899-5760-3
[32] Seedorff E., Dilles J.H., Proffett J.M. Jr., Einaudi M.T., Zurcher L., Stavast W.J.A., Johnson D.A., Barton M.D., "Porphyry related deposits: Characteristics and origin of hypogene features", in: Hedenquist J.W., Thompson J.F.H., Goldfarb R.J., Richards J.P. (Eds.), Economic Geology: 100th Anniversary Volume, Littleton, Colorado (2005) 251–298. https://doi.org/10.5382/AV100.10
[33] Titley S.R., Beane R.E., "The porphyry copper deposit at Bingham, Utah: geologic and geochemical studies", Economic Geology 76 (1981) 857–891.
[34] Sillitoe R.H., "Supergene enrichment and gossan zones in porphyry copper deposits", in: Hedenquist J.W., Thompson J.F.H., Goldfarb R.J., Richards J.P. (Eds.), Economic Geology: 100th Anniversary Volume (2005) 811–844.
[35] Hosseinzadeh M., Asadi A., Simmonds V., Leybourne M., Moayyed M., Vahed Y., "The Jalilabad copper deposit in the Tarom-Hashjin magmatic belt, NW Iran: Epithermal or porphyry deposit? Evidence from geology, alteration, geochemistry, fluid inclusions, and stable isotope studies", Acta Geochimica (2025). https://doi.org/10.1007/s11631-025-00806-6
[36] Tunc A., She Z., Zhu Y., Cao K., Deevsalar R., Feng Y., Pan Y., "Nature and origin of dolomite-hosted Th-U-HREE mineralization in the Tethyan Metallogenic Belt, Biga Peninsula, Northwestern Türkiye", Ore Geology Reviews 182 (2025) 106671. https://doi.org/10.1016/j.oregeorev.2025.106671.
[37] Codeço M.S., Weis P., Andersen C., "Numerical modeling of structurally controlled ore formation in magmatic-hydrothermal systems", Geochemistry, Geophysics, Geosystems 23 (2022) e2021GC010302. doi:10.1029/2021GC010302.