Mineralogy, geochemistry and genesis of corundum-amesite rich meta-bauxites in the Lavand Deposit, Mahallat, Central Iran

Document Type : Original Article

Authors

1 Department of Earth Sciences, University of Tabriz, Tabriz, Iran

2 2. Exploration Department Expert, Magma ma`dan Arya Company, Shiraz, Iran

Abstract

Lavand bauxite deposit is located about 11 km west of the Mahallat city, in the north of 1:100000 Mahallat Sheet; structurally, it is a part of the Central Iran zone and parts of the Precambrian metamorphism of Golpayegan. Two main bauxite-laterite zones of the Permian age are enclosed between layers of Arkosic sandstone units and yellow marble limestone. This deposit has a wide variety of minerals, including aluminum and iron oxides-hydroxides, silicates, titanium oxides, and carbonates. Corundum and Amesite are the main minerals in this deposit. The index textures of these specimens include oolitic-pisolitic, oolitic-spheroidal and oolitic-spastolitic textures. Lavand bauxites contain 48-56% Al2O3, 3 to 25% Fe2O3, 4 to 18% SiO2 and 1 to 6% TiO2. Based on the Al2O3-Fe2O3-SiO2 Ternary diagrams, this deposit is classified as bauxite and iron bauxite. These Al₂O₃-rich samples formed during the lateritization process. Based on this studiy, Permian basalts and diabase dykes can be considered as the source rock of Lavand meta-bauxite. According to the Eh-pH diagram of natural atmospheric environments and the stability environment of minerals, during the lateritization process, the oxidizing conditions have changed to reducing conditions in a cross-sectional manner. Also, the mineralogical diversity in the region confirms several phases of reduction and oxidation in environment during the evolution process of the Lavand deposit. Therefore, weathering of the source rock and subsequent bauxitization processes have led to the leaching of alkaline and alkaline earth elements from the environment and the bauxite is formed; resulting in the formation of bauxite through diagenetic processes and subsequent metamorphism

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[1] Aydogan M.S., Moazzen M., “Origin and metamorphism of corundum-rich metabauxites at Mt. Ismail in the southern Menderes Massif, SW Turkey”, Resour Geol 62 (2012) 243–262.
[2] Geological and Exploration Organization of Iran”, Geological map 1:100,000 of localities, (in Persian) (2005).
[3] Bardossy G., “Karst bauxites”, Elsevier, Amsterdam (1982) 441 pp.
[4] Reolid M., Abad I., Martin Garcia J. M., “palaeoenvironmental implications of ferruginous deposit related to a Middle-Upper Jurassic discontinuity (Prebtic Zone, Betic Cordillera, Southern Spain)”, Sedimentary Geology 203(2008) 1-16.
[5] Petrascheck W. E., “The genesis of allochthonous karst-type bauxite deposits of southern Europe", Mineralum Deposita 24 (1989) 77-81.
[6] Gu J., Huang Z., Fan H., Jin Z., Yan Z., Zhang J., “Mineralogy, geochemistry, and genesis of lateritic bauxite deposits in the Wuchuan–Zheng'an–Daozhen area, Northern Guizhou Province China”, Journal of Geochemical Exploration, 130(6) (2013) 44–59.
[7] Garrels R. M., Christ C. L., “Solution, Minerals and Equilibria”, Harper and Row, New York (1965) 450 p.
[8] Temur S., Kansun G., “Geology and petrography of the Masatdagi diasporic bauxites, Alanya, Antalya, Turkey”, Journal of Asian Earth Sciences 27 (2006) 512-522.
[9] Schellmann A., “Considerations on the definition and classification of Laterites. Proceeding of International Union of Geological Sciences /United Nations Education, Scientific and Cultural Organization”, Seminar on Laterisation Processes, Paris, and French (1982).
[10] Aleva G. J.  J., “Laterites: Concepts, geology, morphology and chemistry”, ISIRC, Wageningen, (1994)- 169p.
[11] Meyer F.M., Happel U., Hausberg J., Wiechowski A., “The geometry and anatomy of the Pijigaos bauxite deposit”, Venezuela. Ore Geol Rev 20 (2002) 27–54.
[12] Beauvais A., “Palaeoclimats et dynamique d’un paysage cuirasee du Centrafreque. Morphologie, petrologie et geochimie”, PhD, University of Poitiers, Poitiers, France .
[13] Mongelli G., Acquafredda P., “Ferruginous concretions in a Late Cretaceous karst bauxite: composition and conditions of formation”, Chemical Geology, 158(3–4) (1999) 315– 320
[14] Abedini A., Calagri A.A., “Geochemical studies of Permian bauxite-kaolinite deposits in northern Saqez, Kurdistan Province”, Quarterly Journal of Earth Sciences, 20(79) (2011 A)  67-74, (in Persian).
[15] Schroll E., Sauer D., “Beitrag zur geochemie von titan, chrom, nikel, cobalt, vanadium und molibdan in bauxitischen gestemen und problem der stofflichen herkunft des aluminiums”, Travaux de ICSOBA, Zagreb 5 (1968) 83-96.
[16] Emamalipour A., Mirmohammadi M.S., “Mineralogy and geochemistry of corundum-bearing metabauxite-laterite of Hyderabad, southeast of Urmia, northwest of Iran (in Persian)", Iranian Journal of Crystallography and Mineralogy, No. 1 (2011) Year 19.
[17] Tardy Y., “Petrology of Laterites and Tropical Solis”, Oxford, UK: IBH Publishing Co. Pvt. Ltd (1997).
[18] Hallberg J. A., “A geochemical aid to igneous rocks identification in deeply weathered terrain”, Journal of Geochemical Exploration 20, 1- 8.  Halvac, J., 1983 -The technology of glass and ceramics: An introduction. Glass Science Technology (1984) 431p.