اثر اتیلن گلیکول و سولفات دو دسیل سدیم بر ویژگی‌های ساختاری و فوتوکاتالیزوری فریت‌بیسموت

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه شهید چمران اهواز

چکیده

در این پژوهش، اثر روکنشگر در سطح (روکنشگر) بر ویژگی­های ساختاری و فوتوکاتالیزوری فریت بیسموت ساخته شده به روش گرمابی در دمای °C 180 و غلظت 4 مولار بررسی شد. روکنشگر­هایی که در این پژوهش مورد بررسی شدند اتیلن گلیکول و سولفات دودسیل سدیم بودند. نتایج تحلیل الگوهای پراش پرتوی ایکس (XRD) نشان داد که نمونه­ها دارای ساختار پرووسکایت لوزی رخ اعوجاج یافته با گروه فضاییR3c هستند و هم­چنین فریت­بیسموت با خلوص بالا در دمای°C  180 و غلظت 4 مولار بدون حضور روکنشگر ساخته­ شد. نتایج تصاویر میکروسکوپ الکترونی نشر میدانی (FESEM) نشان داد که اندازه ذرات با حضور روکنشگر کاهش یافته است. هم­چنین ویژگی­های نوری و فوتوکاتالیزوری نمونه­ها نیز براساس طیف­سنجی فرابنفش-مرئی (UV-vis) بررسی شد. نتایج نشان داد که اندازه گاف نوری در حضور روکنشگر به حدود 6/1 الکترون ولت کاهش یافته است. ویژگی­های فوتوکاتالیزوری نمونه­ها نیز در رنگ قرمز کنگو در غلظت ppm10 بررسی گردید و نتایج نشان داد که فریت­بیسموت ساخته شده در حضور سولفات دودسیل سدیم بیشترین تخریب را داشته است.       

کلیدواژه‌ها

عنوان مقاله [English]

The effect of ethylene glycol and sodium dicalcyl sulfate on the structural and photocatalytic properties of BiFeO3 nanopaticles

نویسندگان [English]

  • Helfi
  • Mousavi Ghahfarokhi
  • Zargar Shoushtari
چکیده [English]

In this study, the effect of surfactant on the structural and photocatalytic properties of bismuth ferrite made (BiFeO3) by hydrothermal method at a temperature of 180 °C and a concentration of 4 M was investigated. The surfactants studied in this paper are ethylene glycol and sodium dodecyl sulfate. The results of diffraction pattern analysis showed that the samples have a rhombic perovskite structure distorted with space group < /span> R3c. Also, high purity bismuth ferrite was made at 180 °C and 4M concentration without the presence of surfactant. FESEM results showed that the particle size decreased with the presence of surfactant. The optical and photocatalytic properties of the samples were also investigated by UV-Visible analysis. The results showed that the amount of optical gap increased in the presence of surfactant and was recorded in the range of 2.7-2.8 eV for these samples. The photocatalytic properties of the samples were also investigated in Congo red at a concentration of 10 ppm. The results showed that ferrite bismuth made in the presence of sodium dodecyl sulfate had the most damage.
 

کلیدواژه‌ها [English]

  • Surfactant
  • multiferroic
  • bismuth ferrite
  • hydrothermal
  • photocatalyst

مراجع

  1. [1] Schmid H., "Multi-ferroicmagnetoelectric,." Ferroelectrics 162, 317-338 (1994). [DOI:10.1080/00150199408245120]
  2. [1] Schmid H., "Multi-ferroicmagnetoelectric,." Ferroelectrics 162, 317-338 (1994). [DOI:10.1080/00150199408245120]
  3. [2] Biasotto G., Simões A. Z., Foschin C., " A novel synthesis of perovskite bismuth ferrite
  4. [2] Biasotto G., Simões A. Z., Foschin C., " A novel synthesis of perovskite bismuth ferrite
  5. nanoparticles" Processing and Application of Ceramics 5 ,171-179 (2011). [DOI:10.2298/PAC1103171B]
  6. nanoparticles" Processing and Application of Ceramics 5 ,171-179 (2011). [DOI:10.2298/PAC1103171B]
  7. [3] Wei W., Xuan H., Wang L., Zhang Y., Shen K., "The magnetoelectric coupling in rhombohedral-tetragonal phases coexisted Bi0.84Ba0.20FeO3", Physica B: Condensed mater 407, 2243 (2012). [DOI:10.1016/j.physb.2012.03.007]
  8. [3] Wei W., Xuan H., Wang L., Zhang Y., Shen K., "The magnetoelectric coupling in rhombohedral-tetragonal phases coexisted Bi0.84Ba0.20FeO3", Physica B: Condensed mater 407, 2243 (2012). [DOI:10.1016/j.physb.2012.03.007]
  9. [4] Makhdoom A. R., Akhtar M. J., Rafiq M. A., " Investigation of Transport Behavior in Ba Doped BiFeO3,", Ceramics International,No. 38, 3829 (2012). [DOI:10.1016/j.ceramint.2012.01.032]
  10. [4] Makhdoom A. R., Akhtar M. J., Rafiq M. A., " Investigation of Transport Behavior in Ba Doped BiFeO3,", Ceramics International,No. 38, 3829 (2012). [DOI:10.1016/j.ceramint.2012.01.032]
  11. [5] Ruette B., Zvyagin S., Pyatakov A. P., Bush A., Li, Belotelov J.F. V. I., Viehland D., "Magnetic-Field-Induced Phase Transition in BiFeO3 Observed by High-Field Electron Spin Resonance: Cycloidal to Homogeneous Spin Order,"
  12. [5] Ruette B., Zvyagin S., Pyatakov A. P., Bush A., Li, Belotelov J.F. V. I., Viehland D., "Magnetic-Field-Induced Phase Transition in BiFeO3 Observed by High-Field Electron Spin Resonance: Cycloidal to Homogeneous Spin Order,"
  13. Physics Review B, 69, 064114-064117 ( 2004).
  14. Physics Review B, 69, 064114-064117 ( 2004).
  15. [6] K. H. Wu, Y.C. Chang, T.C. Chang, Y.S. Chiu, T.R. Wu, "Effect of SiO2 content and
  16. [6] K. H. Wu, Y.C. Chang, T.C. Chang, Y.S. Chiu, T.R. Wu, "Effect of SiO2 content and
  17. solution pH IN raw materials on Ni-Zn ferrite magnetic properties", J. Magn. Magn.
  18. solution pH IN raw materials on Ni-Zn ferrite magnetic properties", J. Magn. Magn.
  19. Mater. 283, 380-384 (2004).
  20. Mater. 283, 380-384 (2004).
  21. [7] Wu W., Z.h. Jiang Ch., Roy V.A.L., "Designed synthesis and surface engineering
  22. [7] Wu W., Z.h. Jiang Ch., Roy V.A.L., "Designed synthesis and surface engineering
  23. strategies of magnetic iron oxide nanoparticles for biomedical applications," Nanoscale 8, 19421-19474 (2016). [DOI:10.1039/C6NR07542H]
  24. strategies of magnetic iron oxide nanoparticles for biomedical applications," Nanoscale 8, 19421-19474 (2016). [DOI:10.1039/C6NR07542H]
  25. [8] Bayoumy W.A.A., "Synthesis and characterization of nano-crystalline Zn-substituted
  26. [8] Bayoumy W.A.A., "Synthesis and characterization of nano-crystalline Zn-substituted
  27. Mg-Ni-Fe-Cr ferrites via surfactant-assisted route", J. Mol. Struct. 1056-1057, 285-291
  28. Mg-Ni-Fe-Cr ferrites via surfactant-assisted route", J. Mol. Struct. 1056-1057, 285-291
  29. (2014).
  30. (2014).
  31. [9] Ferńandez Cirelli A., Ojeda C., Castro M.J.L., Salgot M., "Surfactants in sludgeamended agricultural soils", a review, Environ. Chem. Lett. 6, 135-148 (2008). [DOI:10.1007/s10311-008-0146-1]
  32. [9] Ferńandez Cirelli A., Ojeda C., Castro M.J.L., Salgot M., "Surfactants in sludgeamended agricultural soils", a review, Environ. Chem. Lett. 6, 135-148 (2008). [DOI:10.1007/s10311-008-0146-1]
  33. [10] Mahato R.I., Narang A.S., "Pharmaceutical Dosage Forms and Drug Delivery ,"CRC Press, 180-191(2011). [DOI:10.1201/b12122]
  34. [10] Mahato R.I., Narang A.S., "Pharmaceutical Dosage Forms and Drug Delivery ,"CRC Press, 180-191(2011). [DOI:10.1201/b12122]
  35. [11] Dominguez A., Fernandez A., Gonzalez N., Iglesias E., Montenegro L., "Determination of critical micelle concentration of some surfactants by three techniques", J. Chem. Educ. 74, 1227 (1997). [DOI:10.1021/ed074p1227]
  36. [11] Dominguez A., Fernandez A., Gonzalez N., Iglesias E., Montenegro L., "Determination of critical micelle concentration of some surfactants by three techniques", J. Chem. Educ. 74, 1227 (1997). [DOI:10.1021/ed074p1227]
  37. [12] Forney C.E., Glatz Ch.E., "Extraction of charged fusion proteins in reversed micelles:
  38. [12] Forney C.E., Glatz Ch.E., "Extraction of charged fusion proteins in reversed micelles:
  39. comparison between different surfactant systems," Biotech. Prog. 11, 260-264 (1995). [DOI:10.1021/bp00033a003]
  40. comparison between different surfactant systems," Biotech. Prog. 11, 260-264 (1995). [DOI:10.1021/bp00033a003]
  41. [13] Kang K. H., Un H., Kim, K.H. Lim, N.H. Jeong, "Mixed micellization of anionic ammonium dodecyl sulfate and cationic octadecyltrimethyl ammonium chloride", Bull.Kore. Chem. Soc. 22, 1009-1014 (2001).
  42. [13] Kang K. H., Un H., Kim, K.H. Lim, N.H. Jeong, "Mixed micellization of anionic ammonium dodecyl sulfate and cationic octadecyltrimethyl ammonium chloride", Bull.Kore. Chem. Soc. 22, 1009-1014 (2001).
  43. [14] Malik M.A., Khan Z., "Permanganate transfer and reduction by D-glucose in benzene-cetyltrimethylammoniumbromide aqueous solution: a kinetic study", Int. J.Chem. Kinet. 40, 496-503 (2008). [DOI:10.1002/kin.20325]
  44. [14] Malik M.A., Khan Z., "Permanganate transfer and reduction by D-glucose in benzene-cetyltrimethylammoniumbromide aqueous solution: a kinetic study", Int. J.Chem. Kinet. 40, 496-503 (2008). [DOI:10.1002/kin.20325]
  45. [15] Nejati K., Zabihi R., "Preparation and magnetic properties of nano size nickel ferrite
  46. [15] Nejati K., Zabihi R., "Preparation and magnetic properties of nano size nickel ferrite
  47. particles using hydrothermal method", Chem. Cent. J. 6, 23 (2012).
  48. particles using hydrothermal method", Chem. Cent. J. 6, 23 (2012).
  49. [16] Kamel Attar Kar M., Manteghi F., Fazaeli R., "Investigation of effect of using organic
  50. [16] Kamel Attar Kar M., Manteghi F., Fazaeli R., "Investigation of effect of using organic
  51. surfactant in structural properties of CuFe2O4 nanoparticles", The 19th Int.Electronic Conference on Synthetic Organic Chemistry (2015).
  52. surfactant in structural properties of CuFe2O4 nanoparticles", The 19th Int.Electronic Conference on Synthetic Organic Chemistry (2015).
  53. [17] Kamel Attar Kar M., Manteghi F., Fazaeli R., "Synthesis of NiFe2O4 nanoparticles by
  54. [17] Kamel Attar Kar M., Manteghi F., Fazaeli R., "Synthesis of NiFe2O4 nanoparticles by
  55. organic surfactants-assisted sol-gel auto-combustion method, characterization and
  56. organic surfactants-assisted sol-gel auto-combustion method, characterization and
  57. determination of band gap", The 19th Int. Electronic Conference on Synthetic Organic Chemistry. (2015).
  58. determination of band gap", The 19th Int. Electronic Conference on Synthetic Organic Chemistry. (2015).
  59. [18] Chen Zh., Jin W., Lu Zh., "Ferromagnetic and photocatalytic properties of pure BiFeO3
  60. [18] Chen Zh., Jin W., Lu Zh., "Ferromagnetic and photocatalytic properties of pure BiFeO3
  61. powders synthesized by ethylene glycol assisted hydrothermal", J Mater Sci: Mater Electron
  62. powders synthesized by ethylene glycol assisted hydrothermal", J Mater Sci: Mater Electron
  63. method, 16 November (2014).
  64. method, 16 November (2014).
  65. [19] Mousavi Ghahfarokhi S.E., Mohammadzadeh Shobegar E., " An investigation of the ethylene glycol surfactant on the structural, microstructure,magnetic and optical properties of SrFe2O4 nanoparticles", Journal of Magnetism and Magnetic Materials, 16 September (2019). [DOI:10.1016/j.jmmm.2019.165866]
  66. [19] Mousavi Ghahfarokhi S.E., Mohammadzadeh Shobegar E., " An investigation of the ethylene glycol surfactant on the structural, microstructure,magnetic and optical properties of SrFe2O4 nanoparticles", Journal of Magnetism and Magnetic Materials, 16 September (2019). [DOI:10.1016/j.jmmm.2019.165866]
  67. [20] molahasani N., "Effect of polyethylene glycol with different molecular weights on the energy gap of zinc oxide nanoparticles ", 7th International Conference of the Chemistry and Chemical Engineering, Tehran , July, (2020).
  68. [20] molahasani N., "Effect of polyethylene glycol with different molecular weights on the energy gap of zinc oxide nanoparticles ", 7th International Conference of the Chemistry and Chemical Engineering, Tehran , July, (2020).
  69. [21] Kumari L., Li W.Z., Kulkarni Sh., Wu K.H., Chen W., Wang Ch., Vannoy Ch.H.,
  70. [21] Kumari L., Li W.Z., Kulkarni Sh., Wu K.H., Chen W., Wang Ch., Vannoy Ch.H.,
  71. Leblanc R.M., "Effect of surfactants on the structure and morphology of magnesiumborate hydroxide nanowhiskers synthesized by hydrothermal route", Nanoscale Res.Lett. 5, 149-157 (2010). [DOI:10.1007/s11671-009-9457-9]
  72. Leblanc R.M., "Effect of surfactants on the structure and morphology of magnesiumborate hydroxide nanowhiskers synthesized by hydrothermal route", Nanoscale Res.Lett. 5, 149-157 (2010). [DOI:10.1007/s11671-009-9457-9]
  73. [22] Andoulsi R., Horchani-Naifer K., Ferid M., "Structural and electrical properties of calcium substituted lanthanum ferrite powders", J. Powder Technol. 230, 183-187 (2012). [DOI:10.1016/j.powtec.2012.07.026]
  74. [22] Andoulsi R., Horchani-Naifer K., Ferid M., "Structural and electrical properties of calcium substituted lanthanum ferrite powders", J. Powder Technol. 230, 183-187 (2012). [DOI:10.1016/j.powtec.2012.07.026]
  75. [23] Ghosh S., Dasgupta S., Sen A., Maiti H. S., "Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route", J. Am. Ceram. Soc, 88, 1349-1352 (2005). [DOI:10.1111/j.1551-2916.2005.00306.x]
  76. [23] Ghosh S., Dasgupta S., Sen A., Maiti H. S., "Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route", J. Am. Ceram. Soc, 88, 1349-1352 (2005). [DOI:10.1111/j.1551-2916.2005.00306.x]
  77. [24] Muneeswaran M., Jegatheesan P., Giridharan N. V., "Synthesis of nanosized BiFeO3 powders by co-precipitation", J. Exp. Nanosci., 8, 341-346 (2013). [DOI:10.1080/17458080.2012.685954]
  78. [24] Muneeswaran M., Jegatheesan P., Giridharan N. V., "Synthesis of nanosized BiFeO3 powders by co-precipitation", J. Exp. Nanosci., 8, 341-346 (2013). [DOI:10.1080/17458080.2012.685954]
  79. [25] Farhadi S., Zaidi M., "Bismuth ferrite (BiFeO3) nanopowder prepared by sucrose-assisted combustion method: A novel and reusable heterogeneous catalyst for acetylation of amines, alcohols and phenols under solvent-free conditions", J. Mol. Catal. A: Chem. 299, 18-25 (2009). [DOI:10.1016/j.molcata.2008.10.013]
  80. [25] Farhadi S., Zaidi M., "Bismuth ferrite (BiFeO3) nanopowder prepared by sucrose-assisted combustion method: A novel and reusable heterogeneous catalyst for acetylation of amines, alcohols and phenols under solvent-free conditions", J. Mol. Catal. A: Chem. 299, 18-25 (2009). [DOI:10.1016/j.molcata.2008.10.013]
  81. [26] Simões A.Z., Stojanovic B.D., Ramirez M.A., Cavalheiro A.A., Longo E., Varela J.A., "Lanthanum-dopedBi4Ti3O12 prepared by the soft chemical method: Rietveld analysis and piezoelectric properties", Ceram. Int., 34, 257-261 (2008) [DOI:10.1016/j.ceramint.2006.09.019]
  82. [26] Simões A.Z., Stojanovic B.D., Ramirez M.A., Cavalheiro A.A., Longo E., Varela J.A., "Lanthanum-dopedBi4Ti3O12 prepared by the soft chemical method: Rietveld analysis and piezoelectric properties", Ceram. Int., 34, 257-261 (2008) [DOI:10.1016/j.ceramint.2006.09.019]
  83. [27] Akbari S., Masoudpanah S.M., Mirkazemi S.M., Aliyan N., "PVA assisted coprecipitation synthesis and characterization of MgFe2O4 nanoparticles", Ceram.Int. 43, 6263-6267 (2017). [DOI:10.1016/j.ceramint.2017.02.030]
  84. [27] Akbari S., Masoudpanah S.M., Mirkazemi S.M., Aliyan N., "PVA assisted coprecipitation synthesis and characterization of MgFe2O4 nanoparticles", Ceram.Int. 43, 6263-6267 (2017). [DOI:10.1016/j.ceramint.2017.02.030]
  85. [28] Simchi A., " Introduction to Nanoparticles: Properties, Methods of produce and
  86. [28] Simchi A., " Introduction to Nanoparticles: Properties, Methods of produce and
  87. Application", publication university sharif, Iran, (2008).
  88. Application", publication university sharif, Iran, (2008).
  89. [29] Kazeminezhad I., Sadollahkhani A., "Influence of pH on the photocatalytic activity of ZnO nanoparticles", Journal of Materials Science: Materials in Electronics 27, 4206-4215 (2016). [DOI:10.1007/s10854-016-4284-0]
  90. [29] Kazeminezhad I., Sadollahkhani A., "Influence of pH on the photocatalytic activity of ZnO nanoparticles", Journal of Materials Science: Materials in Electronics 27, 4206-4215 (2016). [DOI:10.1007/s10854-016-4284-0]
  91. [30] Asahi R., Morikawa T., Ohwaki T., Aoki K., Taga Y., "Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides", Science 293, 269-271 (2001). [DOI:10.1126/science.1061051]
  92. [30] Asahi R., Morikawa T., Ohwaki T., Aoki K., Taga Y., "Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides", Science 293, 269-271 (2001). [DOI:10.1126/science.1061051]
  93. [31] Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W., " Environmental Applications of Semiconductor Photocatalysis", Chem.Rev. 95, 69-96 (1995) [DOI:10.1021/cr00033a004]
  94. [31] Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W., " Environmental Applications of Semiconductor Photocatalysis", Chem.Rev. 95, 69-96 (1995) [DOI:10.1021/cr00033a004]
  95. [32] Li S., Lin Y. H., Zhang B. P., Wang Y., Nan C. W., "Photocatalytic and magnetic behaviors observed in nanostructured BiFeO3 particles," Journal of Applied Physics 105, 056105 (2009). [DOI:10.1063/1.3080131]
  96. [32] Li S., Lin Y. H., Zhang B. P., Wang Y., Nan C. W., "Photocatalytic and magnetic behaviors observed in nanostructured BiFeO3 particles," Journal of Applied Physics 105, 056105 (2009). [DOI:10.1063/1.3080131]
  97. [33] Zhang Z.B., Wang C.C., Zakaria R., Ying J.Y., " Role of Particle Size in Nanocrystalline TiO2-Based Photocatalysts," J. Phys. Chem. B102, 10871-10878 (1998). [DOI:10.1021/jp982948+]
  98. [33] Zhang Z.B., Wang C.C., Zakaria R., Ying J.Y., " Role of Particle Size in Nanocrystalline TiO2-Based Photocatalysts," J. Phys. Chem. B102, 10871-10878 (1998). [DOI:10.1021/jp982948+]
  99. [34] Baiju K.V., Shukla S., Sandhya K.S., James J., Warrier K.G.K., "Photocatalytic Activity of Sol-Gel Derived NanocrystallineTitania", J. Phys. Chem. C 111, 7612-7622, 2007 (3.396). [DOI:10.1021/jp070452z]
  100. [34] Baiju K.V., Shukla S., Sandhya K.S., James J., Warrier K.G.K., "Photocatalytic Activity of Sol-Gel Derived NanocrystallineTitania", J. Phys. Chem. C 111, 7612-7622, 2007 (3.396). [DOI:10.1021/jp070452z]
  101. [35] Chen X., Shen S., Guo L., Mao S.S., "Semiconductor-based Photocatalytic Hydrogen Generation" Chem. Rev. 110, 6503-6570 (2010). [DOI:10.1021/cr1001645]
  102. [35] Chen X., Shen S., Guo L., Mao S.S., "Semiconductor-based Photocatalytic Hydrogen Generation" Chem. Rev. 110, 6503-6570 (2010). [DOI:10.1021/cr1001645]

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  • تاریخ دریافت: 04 اردیبهشت 1401
  • تاریخ بازنگری: 01 تیر 1401
  • تاریخ پذیرش: 21 تیر 1401

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