سنتز و تعیین ساختار بلوری کمپلکس جیوه(II) Hg(Meca2en)I2

نویسندگان

1 دانشگاه گلستان

2 انستیتو فیزیک ASCR

چکیده

کمپلکس جیوه (II) Hg(Meca2en)I2 با لیگاند دو دندانه­ای Meca2en = N,N′-bis[(E)-2-benzylidenepropylidene]ethane-1,2-diamine سنتز و به کمک روشهای تجزیه عنصری و طیف­سنجی 1H-NMR مورد شناسایی قرار گرفته است. ساختار بلوری این ترکیب به کمک تکنیک پراش پرتو ایکس تک­بلور شناسایی شد. این ترکیب به صورت سیستم مونو­کلینیک و گروه فضایی P21/n متبلور می شود. لیگاند باز­شیف به­صورت دودندانه و کی­لیت از طریق دو اتم نیتروژن به مرکز جیوه (II) متصل می­شود.

کلیدواژه‌ها


عنوان مقاله [English]

Synthesis and crystal structure of mercury (II) complex Hg (Meca2en) I2

چکیده [English]

The mercury (II) complex, Hg (Meca2en)I2 (1), containing bidentate Schiff base ligand  Meca2en = N,N′-bis[(E)-2-benzylidenepropylidene]ethane-1,2-diamine, has been synthesized and characterized by elemental analyses (CHN) and 1H-NMR spectroscopy. The crystal structure of 1 was determined using single-crystal X-ray diffraction. Structural investigation shows that 1 crystallizes in a monoclinic system, with space group P < /em>21/n. The Schiff base ligand Meca2en acts as a bidentate ligand coordinating via two N atoms to mercury (II) ion.

کلیدواژه‌ها [English]

  • Mercury (II) complex
  • Schiff base
  • crystal structure
  • monoclinic
[1] Laye R.H., “Syntheses and photophysical properties of a series of [2:2] silver(I) metallocycles”, Inorganica Chimica Acta 360 (2007) 439-447.

[2] Zhang G., Yang G., Ma J.S., “A novel luminescent metallomacrocycle assembled by silver nitrate and 1,3-bis(pyrrol-2-yl-methyleneamino)propane”, Inorganic Chemistry Communications 7 (2004) 994-997.

[3] Dolaz M., McKee V., Golcu A., Tumer M., “Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes”, Spectrochimica Acta A71 (2009) 1648-1654.

[4] Mukherjee A., Chakrabarty R., Ng S.W., Patra G.K., “The syntheses, characterizations, X-ray crystal structures and properties of Cu(I) complexes of a bis-bidentate schiff base ligand”, Inorganica Chimica Acta 363 (2010) 1707-1712.

[5] Ardizzoia G.A., Brenna S., Castelli F., Galli S., “Copper(I)-imine complexes: Synthesis and catalytic activity in olefin cyclopropanation”, Inorganica Chimica Acta 362 (2009) 3507-3512.

[6] Sawant S.K., Gaikwad G.A., Sawant V.A., Yamgar B.A., Chavan S.S., “Synthesis, characterization and catalytic study of Schiff base copper(I) complexes for the amination of aryl halide”, Inorganic Chemistry Communications 12 (2009) 632-635.

[7] Chattopadhyay S., Bhar K., Khan S., Mitra P., Butcher R.J., Ghosh B.K., “Synthesis, structure and luminescence behaviour of bis(tridentate) Schiff base bridged dinuclear lead(II) pseudohalides”, Journal of Molecular Structure 966 (2010) 102-106.

[8] Shi Q., Xu L., Ji J., Li Y., Wang R., Zhou Z., Cao R., Hong M., Chan A.S.C., “Syntheses and structures of two anion-templated dinuclear cadmium complexes with diamino-binaphthyl Schiff bases as ligands”, Inorganic Chemistry Communications 7 (2004) 1254-1257.

[9] Chowdhury H., Ghosh R., Rahaman S.H., Ghosh B.K., “Syntheses, X-ray structures and properties of a dinuclear cadmium(II)azido and a polymeric cadmium(II)thiocyanato compounds containing bis(tridentate) congregators”, Polyhedron 26 (2007) 5023-5029.

[10] Morshedi M., Amirnasr M., Slawin A.M.Z., Woollins J.D., Khalaji A.D., “Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca2-dapte: Mononuclear and dinuclear copper (I) complexes [Cu (ca2dapte)] ClO4 and [{Cu (PPh3) (X)}2(ca2dapte)] (X = I and Br)”, Polyhedron 28 (2009) 167-171.

[11] Komatsu H., Ochiai B., Hino T., Endo T., “Thermally latent reaction of hemiacetal ester with epoxide controlled by Schiff-base–zinc chloride complexes with tunable catalytic activity”, Journal of Molecular Catalysis A Chemical 273 (2007) 289-297.

[12] Khalaji A.D., Grivani G., Rezaei M., Fejfarova K., Dusek M., “Synthesis and spectral characterization of mercury(II) complexes with the bidentate Schiff base ligand N,N′-bis(2,3-dimethoxybenzylidene)-1,2-diaminoethane: The crystal structures of [Hg((23-MeO-ba)2en)I2] and [Hg((23-MeO-ba)2en)Br2]”, Polyhedron 30 (2011) 2790-2794.

[13] Amirnasr M., Mahmoudkhani A.H., Gorji A., Dehghanpour S., Bijanzadeh H.R., “Cobalt(II), nickel(II), and zinc(II) complexes with bidentate N,N′-bis(β-phenylcinnamaldehyde)-1,2-diiminoethane Schiff base: synthesis and structures”, Polyhedron 21 (2002) 2733-2742.

[14] Khalaji A.D., Weil M., Grivani G., Jalali Akerdi S., “Synthesis, characterization, and crystal structure of two zinc (II) halide complexes with the symmetrical bidentate Schiff-base ligand (3,4-MeO-ba)2en”, Monatshefte Chemistry 141 (2010) 539-543.

[15] Montazerozohori M., Khani S., Tavakol H., Hojjati A., Kazemi M., “Synthesis, spectroscopic and thermal studies of some IIB group complexes with a new N2-Schiff base ligand”, Spectrochimica Acta A81 (2011) 122-127.

[16] Montazerozohori M., Joohari S., Musavi S.A., “Synthesis and spectroscopic studies of some cadmium (II) and mercury (II) complexes of an asymmetrical bidentate Schiff base ligand“, Spectrochimica Acta A73 (2009) 231-237.

[17] Drew M.G.B., De S., Datta D., “Stereochemically non-rigid helical mercury (II) complexes”, Inorganica Chimica Acta 362 (2009) 2487-2491.

[18] Chattopadhyay S., Bhar K., Das S., Satapathi S., Fun H.K., Mitra P., Ghosh B.K., “Synthesis, molecular and crystalline architectures, and properties of novel bis(bidentate) and bis(tridentate) Schiff base bridged dinuclear mercury(II)pseudohalides: Control of coordination numbers by varying denticities”, Polyhedron 29 (2010) 1667-1675.

[19] Khalaji A.D., Ng S.W., “N,N′-Bis[(E)-2-Benzylidenepropylidene]-ethane-1,2-diamine" Acta Crystallographica E64 (2008) o1771.

[20] Burla M.C., Camalli M, Carrozzini B, Cascarano G, Giacovazzo C, Polidori G, Spagna R., “SIR2002 : the program”, Journal of Applied Crystallography 36 (2003) 1103.

[21] Petricek V, Dusek M, Palatinus L. Jana2006., “Structure determination software programs”. Institute of Physics, Praha, Czech Republic (2008).

[22] Farrugia L.J., “ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)”, Journal of Applied Crystallography 30 (1997) 565.