هم نهشت کردن زئولیت در اثر تغییر فاز گرمابی کائولینیت تحت تاثیر محلول‌های باریم و سدیم‌دار

نویسندگان

دانشگاه تهران

چکیده

 در بررسی فرایند تغییر فاز کائولینیت (H4Al2Si2O9)، تحت تاثیر شاره­های حاوی کاتیون­های Na+   و Ba2+ با غلظت­های متفاوت از 25/1 تا 5 مول، در دمای۱۵۰درجه­ی سانتی­گراد و زمان واکنشی ۹۶ ساعت، محلول­های قلیایی سدیک به­عنوان خاستگاه یون­های Na+  و OH- و محلول نمک کلرور باریم (BaCl2.2H2O) به­عنوان خاستگاه یون­هایBa2+  وCl-  استفاده شدند. نتایج این آزمایش­ها نشان داد که کانی­های هارموتوم (BaAl2Si6O16.6H2O)، فوجاسیت (Na20[Al60Si132O384].235H2O) و هیدروکسی سودالیت (Na6[AlSiO4]6.8H2O) از کائولینیت سنتز می­شود. این نتایج، فرایند انحلال- رسوب را پیشنهاد می­کند. یکی دیگر از هدف­های این بررسی بازسازی شرایط طبیعی سنتز این کانی­ها در محیط آزمایشگاهی است. در این سری از آزمایش­ها شرایط گرمابی مورد نیاز به­وسیله­ی اتوکلاوهای گرمابی برقرار شده و تغییر فاز صورت گرفته با بررسی نمودارهای XRD از نمونه­ی اولیه و همنهشتی، و تصاویر ریخت­شناسی بلورها با استفاده از میکروسکوپ الکترونی (SEM) به­دست آمد.

کلیدواژه‌ها


عنوان مقاله [English]

Mineralogical study of intrusive rocks and alteration zones and compliance with geochemical data in Gazu Cu deposit, southwest Deyhouk

چکیده [English]

Gazu copper deposit is located in the boundary of Tabas and Lut block, 65km southeast of Tabas and 15km southwest of Deyhouk. The dominant lithology in the area consists of Shotori dolomite and limestone and Shemshak shale and sandstone.  Intrusive rocks with intermediate composition are widespread and numerous in the area. They consist of diorite, monzonite, and quartz monzonite to granite. Mineralogy of this intrusive are quartz, plagioclase, K spar, hornblende and slightly biotite and pyroxene. Accessory minerals consist of apatite and zircon. Main alterations in the area consist of: QSP, silicified carbonate, propylitic and skarnification. Main secondary minerals consist of sericite, quartz, carbonate, chlorite, epidote and calcsilicate minerals such as garnet, wollastonite, idocrase ets. In a 70 km2 area, mineralized and alteration zones exists in at least four locations: GA.I-GA.II-GA.III-GA.IV. Mineralization is frequently in the form of disseminated, stockwork, and less in hydrothermal breccias. Primary minerals consist of pyrite, chalcopyrite, sphalerite and barite, and secondary minerals are chalcocite, covellite, cuprite, malachite, chrysocolla, atacamite and turquoise. Considering the, presence of various intermediate to acidic intrusive rocks, type and extension of alteration, type and form of mineralization and geochemical data, Gazu deposit is introduced as a first porphyry copper mineralization and related skarn in Tabas block.   

کلیدواژه‌ها [English]

  • Gazu deposit
  • Tabas block
  • porphyry Cu
  • disseminated mineralization
  • stockwork mineralization
[1] Kumara H., Zimmea A., Rescheetilowski W., “ Chemical Modification Effect on the Sorption Capacities of natural Clinoptilite” , Chem Eng. Tecno. (2003) 25:301-305

[2] Navrotsky A., Sun P., “ Enthalpy of formation and dehydration of alkaline earth cation exchanged zeolite beta” , Microporous and Mesoporous Materials.(2007) doi: 10/1016/j, pages: 1-9

[3] Cronstedt Kong A.F., Vet. Acad. Handlingar 17 (1756) 120.

[4] Claire Deville H.C.R. de St, Séances Acad. Sci. 54 (1862) 324

[5] Breck D.W., “ Zeolite Molecular Sieves: Structure Chemistry and Use” , Wiley, Interscience., New York. (1974) 771p.

[6] Bentabol M.., Ruiz Cruz M.D., Huertas F.J ., Linares J., “ Chemical and structuralvariablity of illitic phases formed from kaolinite in hydrothermal conditions” , Appl. Clay Sci. (2006) 32, 111–124.

[7] Chermak J.A., Rimstidt J.D., “The hydrothermal transformationrate of kaolinite to muscovite/illite” , Geochim. Cosmochim.(1990) Acta54, 2979–2990.

[8] Velde B., “Eperimental determination of muscovite polymorph stabilities”, Amer. Mineral.50, (1965) 436-449.

[9] Huang W. J., “ The formation of illitic clays fromkaolinite in KOH solution from 2258C to 3508C” , Clays and Clay Minerals. (1993) 6, 645±654.

[10] Riose C.A., Williams C.D., Maple M.J., “ Synthesise of Zeolites and Zeotypes by Hidrothermal transformation of kaolinaite and metakaolinite” , Bucaramange, Colombia. (2007) pp. 15-26

[11] Bauer A., Velde B., Berger G., “Kaolinite transformation in high molar KOH solutions” , Appl. Geochem., inpress. (1998).

[12] James E. McEvoy., Morton Pa., “Synthetic Harmotome from DE- Exothermed kaolin” , assignor to Air Products and Chemicals, Inc., Philadelphia, Pa., a corporation of Delaware. No Drawing. Ser. (1967) No 665, 961.

[13] Tutti F., Kamyab S . M ., Barghi M .A., Badiei A., “ Phase transition of clinoptilolite to edingtonite and harmotome in the alkaline hydrothermal conditions” , Journal of Crystalography and Mineralogy” , (2012) Vol.19, No.4.

[14] Perrotta A. J., “Alow-temperature synthesise of a harmotome-type zeolite” , Amer. Min. (1976) 61, 495-6.

[15] Smith J.V., “Topochemistry of zeolites and related minerals” , Topology and geometry, Chem

Rev. (1988) 88:149-189.

[16] Bayati B., Babaluo A . A., Ahmadian Namini P., “Synthesis and Seeding Time Effect on the Inter-Crystalline Structure of Hydroxy-Sodalite Zeolite Membranes by Single Gas (H2and N2) Permeation” , Nanostructure Materials Research Center (NMRC), Iran. J. Chem. Chem. Eng. (2009) Vol. 28, No. 4.