Effect of Sintering Temperature on Structural and Electromagnetic Properties of Yttrium Iron Garnet Nanostructures Synthesized by Sol-Gel Method

Document Type : Research

Authors

Department of Physics, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

Abstract

In this study, the nanostructure of yttrium iron garnet (YIG) synthesized by the sol-gel method and the effect of annealing temperature on its structural, magnetic, and electrical properties were investigated. The dry gel was baked at different temperatures (600 to 1100 °C) and the samples were analyzed using XRD, FTIR, FESEM, VSM, and LCR tests. The results showed that at a temperature, the pure cubic garnet phase was formed and the size of the nanocrystals grew uniformly. At this temperature, the saturation magnetization was maximum and the magnetic and electrical losses were minimum, which led to the improvement of magnetic and electromagnetic properties. Also, the reduction of dielectric losses and the increase in magnetic permeability have made the sample a suitable option for application in high-frequency components such as microwave filters, magnetic sensors, and storage devices.

 

Keywords


[1] M. Niyaifar, M. Dorafshani, A. Hasanpour, “The size-dependent structure and magnetic properties of Yttrium Iron Garnet prepared via sol gel method (in Persian)”, Iranian Journal of Crystallography and Mineralogy, 22(3), 535-540 (2014).
 [2] Niyaifar M., Behmanesh A., Hasanpour A., “An investigation on structural and magnetic properties of praseodymium substituted yttrium iron garnet nanoparticles (in Persian)”, Iranian Journal of Crystallography and Mineralogy, 25(2), 439-448 (2017).
[3] Gorbatov O. I., et al., “Magnetic exchange interactions in yttrium iron garnet: A fully relativistic first-principles investigation,” PHYSICAL REVIEW B, 104, 174401 (2021).
[4] Akhtar M. N., et al., “Structural and magnetic properties of yttrium iron garnet (YIG) and yttrium aluminum iron garnet (YAIG) nanoferrites prepared by microemulsion method”, Journal of Magnetism and Magnetic Materials, 401, 425-431 (2016).
[5] Wei Z., Cuijing G., Rongjin J., Caixiang F., Yanwei Z., “Low-Temperature Synthesis and Microstructure-Property Study of Single-Phase Yttrium Iron Garnet (YIG) Nanocrystals via a Rapid Chemical Coprecipitation”, Materials Chemistry and Physics, 125 (3), 646-651 (2011).
[6] Ghasemi A., Morisako A., “Influence of sintering temperature on the magnetic and electrical properties of nanocrystalline YIG prepared by sol–gel method”, Journal of Alloys and Compounds, 465, 387–392 (2008).
[7] Rushikesh F., et al., “Yttrium iron garnet for hyperthermia applications: Synthesis, characterization and in-vitro analysis”, Materials Science & Engineering. C, Materials for biological applications, 116, 111163 (2020).
[8] Liu J., Jin Q., Wang S., Yu P., Zhang C., Luckhardt C., Su Z., Barua R., Harris V. G., “An insight into formation mechanism of rapid chemical Co-precipitation for synthesizing yttrium iron garnet nano powders”, Materials Chemistry and Physics, 208, 169-176 (2018).
[9] Akhtar M. N., et al., “Structural and Electromagnetic Evaluations of YIG Rare Earth Doped (G, Pr, Ho, Yb) Nanoferrites For High Frequency Applications”, Ceramics International, 43(18), 17032-17040 (2017).
[10] Mousavi Ghahfarokhi S. E., Mohammadzadeh Shobegar E., Zargar Shoushtari E., “Investigation of sintering time on structural, magnetic, and dielectric properties strontium spinel ferrite nanoparticles (SrFe2O4) synthesized by sol-gel method (in Persian)”, Journal of Research on Many-body Systems, 8(17), 167-180 (2018).
[11] Liu J., Jin Q., Wang S., Yu P., Zhang C., Luckhardt C., Su Z., Barua R., Harris V. G., “An insight into formation mechanism of rapid chemical Co-precipitation for synthesizing yttrium iron garnet nano powders”, Materials Chemistry and Physics, 208, 169-176 (2018).
[12] Fernández A., Araujo F. P., Guerra Y., Castro-Lopes S., Matilla-Arias J., de Lima I. S., Silva-Filho E. C., Osajima J. A., Guerrero F., Peña-Garcia R., “Synthesis of coral-like structures of Pr–Yb co-doped YIG: Structural, optical, magnetic and antimicrobial properties”, Journal of Rare Earths, 42(3), 543-554 (2024).
[13] Ristic M., Nowik I., Popovic S., Felner I., Music S., “Influence of synthesis procedure on the YIG formation”, Materials Letters 57, 2584-2590 (2003).
[14] Ravi B. G., Guo X. Z., Yan Q.Y., Gambino R. J., Sampath S., Parise J. B., “Phase evolution and magnetic properties of Al substituted yttrium iron garnet nanopowders and plasma-sprayed coatings”, Surface and Coatings Technology 201, 7597-7605 (2007).
[15] Wang C. C., Yu W. T., “Synthesis of yttrium iron garnet using polymer–metal chelate precursor”, Journal of Colloid and Interface Science 306, 241-247 (2007).
[16] Lee J. W., Oh J. H., “Magneto-optical properties of Bi-YIG nanoparticles dispersed in the organic binder”, Journal of Magnetism and Magnetic Materials 272, 2230-2232 (2004).
[17] El Makdah M. H., El‑Dakdouki M. H., Mhanna R., Al Boukhari J., Awad R., “Effects of neodymium substitution on the structural, optical, and magnetic properties of yttrium iron garnet nanoparticles,” Applied Physics A, 127(5), 304 (2021).
[18] Mousavi Ghahfarokhi S.E., Ranjbar F., Zargar Shoushtari M., “A study of the properties of SrFe12-xCoxO19 nanoparticles”, Journal of Magnetism and Magnetic Materials, 349, 80-87 (2014).
[19] Baladi R., GHEISARI KH., BORHANI N., “The Effect of Synthesis Method on the Structural”, Magnetic and Electrical Properties of Nanostructured Li Ferrite,” NANOSCALE, 6(3), 9-20 (2019).
[20] Ghamari R., Gheisari Kh., “Structure, Microstructure, Magnetic and Electromagnetic Properties Ni-Mn-Zn Ferrite Produced by Glycine-Nitrate Process (in persian)”, journal of New Materials, 7(27), 45-56 (2017).