Geochemical and mineralogy study of the West Rudan ophiolite Melange with emphasis on chromite ore

Document Type : Research

Authors

1 Department of Geology, Faculty of Scinces, Shahid beheshti university, Tehran

2 2- Department of Geology, Faculty of Basic Sciences, University of Sistan and Baluchistan, Zahedan, Iran

Abstract

The Rudan ophiolite complex in Hormozgan Province is located at the boundary between the Zagros structural zone in the south and the Makran-Sanandaj-Sirjan zone in the north. The ultramafic rocks, as the main constituents of this complex, consist mainly of dunite, harzburgite with minor chromitite, which are heavily serpentinized. In this study, geological methods (structural geology and alteration related to mineralization) and geochemical analyses were employed to explore minerals associated with the ophiolite exposures in western Rudan. Geochemical analyses including X-ray fluorescence (XRF), alkaline fusion (AF), induced coupled plasma spectrometry (ICP), and fire assay (FA) were conducted. Results indicate that the western Rudan ophiolites are prospective for magmatic iron, copper, and chromite mineralization. Conversely, they are poor in platinum group elements and gold enrichment. Chromite mineralization occurs in ultramafic units and within the host harzburgite rocks, appearing as disseminated grains, lens-shaped bodies, and vein-veinlet structures. Primary textures of chromite in peridotitic host rocks include granular, mesh, and disseminated types, while secondary textures of chromite-bearing rocks include shear, mylonitic, and cataclastic textures. Based on XRF analysis of chromitite samples, the Cr₂O₃ content ranges from 21.37 to 55.08 wt.%, Fe₂O₃ ranges from 7.13 to 15.88 wt.%, and Al₂O₃ ranges from 5.44 to 16.87 wt.%. The high Cr₂O₃ content in the chromitites of the studied area is consistent with high-grade alpine-type chromitites. Field and laboratory studies show that increased serpentinization correlates with increased chromite potential, especially in harzburgites. The grade of chromite in economic occurrences varies between 20% and 75%, making mining feasible given sufficient reserve.

Keywords


[1] Furnes H., Dilek Y., “Geochemical characterization and petrogenesis of intermediate to silicic rocks in ophiolites”, A global synthesis. Earth-Science Reviews, 166, (2017) 1–37.
[2] Pearce J., “Immobile element fingerprinting of ophiolites”, Elements,10, 2, (2014)  101–108.
[3] Yilmaz A., Yilmaz H., “Ophiolites and ophiolitic mélange of Turkey”, A review. Geological Bulletin of Turkey, 56, (2013) 61–114.
[4] Nicolas A., “Structure of ophiolites and dynamics of oceanic lithosphere”, Kluwer Academic Publishers, Dordrecht, Boston (1989).
[5] Yilmaz A.,  Yilmaz H., “Ophiolites and ophiolitic _melanges of Turkey”, A review. Geological Bulletin of Turkey, 56, (2013) 61–114.
[6] Pearce J. A., Robinson P. T., “Ophiolites: Oceanic crustal analogues. In H. D. Holland & K. K. Turekian (Eds.)”, Treatise on Geochemistry (2nd ed., Vol. 4, pp. 43–88). Elsevier, (2010) https://doi.org/10.1016/B978-008095975-7.00302.
[7] Rajabzadeh M. A., “Chromium and platinum group element mineralization in the Assemion and Neyriz ophiolites”, Zagros belt, Iran (Ph.D. thesis). Institut National Polytechnique de Lorraine, (1998) 358pp.
[8] United States Geological Survey, “Podiform chromite deposits, database and grade and tonnage models”, United States Geological Survey, Virginia, Scientific Investigations Report, 2012–5157 (2012) 45 pp.
[9] Zaccarini F., Garuti G., Pushkarev E., Thalhammer O., “Origin of platinum group minerals (PGM) inclusions in chromite deposits of the Urals”, Minerals (2018) 8, 379.
[10] Boudier F., Nicolas A., “Harzburgite and lherzolite subtypes in ophiolitic and oceanic environments”, Earth Planet. Sci. Lett., 76: (1985) 84-92.
[11] Proenza J.A., “Uvarovite in podiform chromitite: the Moa-Baracoa ophiolitic massif Cuba”, Can. Mineral. 37, (1999) 679–690.
[12] Barnes S. J., Lightfoot P. C, “Chromite: From mantle to ore deposits. Reviews in Economic Geology”, 12, (2005) 1–24.
[13] Butt C. R. M.,  Cluzel D., “Nickel laterite ore deposits”, Weathered serpentinites. Elements, 9(2), (2013),123–128. https://doi.org/10.2113/gselements.9.2.123.
[14] Lewis J. F., Draper G., Proenza J. A., Espaillat J.,  Jimenez J., “Ophiolite-related ultramafic rocks (serpentinites) in the Caribbean Region”, A review of their occurrence, composition, origin, emplace-ment and Ni-laterite soil formation. Geologica Acta, 4, (2006), 237–263.
https://revistes.ub.edu/index.php/GEOACTA/ article/view/105.000000368.
[15] Abedini A., Calagari A.A., "The mineralogy and geochemistry of Permian lateritic ores in east of Shahindezh, West-Azarbaidjan province", Iranian Journal of Crystallography and Mineralogy 20 (2012) 59-72.
[16] Abedini A., Khosravi M., "Geochemical characteristics of aluminum-bearing iron ores: a case study from the Kolijan karst-type bauxite deposit, northwestern Iran", Minerals 14 (2024), 151p.
[17] Alipour S., Abedini A., Abdali S., "Mineralization and Geochemistry of Rare Earth Elements of Heydar-Abad Laterite Horizon, South of Urmia, West Azarbaidjan Province, Iran", Scientific Quarterly Journal of Geosciences 23 (2014) 195-204.
[18] Abedini A., Calagari, A.A., "Rare earth elements geochemistry of Sheikh‐Marut laterite deposit, NW Mahabad, west‐Azarbaidjan Province, Iran", Acta Geologica Sinica‐English Edition 87 (2013), 176-185.
[19] Rajabzadeh M.A., Moosavinasab Z., "Mineralogy and distribution of Platinum-Group--Minerals (PGM) and other solid inclusions in the Faryab ophiolitic chromitites", Southern Iran. Mineralogy and Petrology, 107,6, (2013): 943-962.
[20] Naldrett A.J., Kinnaird J., Wilson A., Yudovskaya M., McQuade S., Chunnett G., Stanley C., "Chromite composition and PGE content of Bushveld chromitites", Part 1—the Lower and Middle Groups. Appl. Earth Sci., 118, (2009) 131–161.
[21] Irvine T.N, "Origin of chromitite layers in the Muskox intrusion and other stratiform intrusions", A new interpretation. Geology (1977) 5, 273.
[22] Barnes S.J., Roeder P., "The range of spinel compositions in terrestrial mafic and ultramafic
Rocks"
, J. Petrol. 42, (2001) 2279–230.
[23] Johan Z., Martin R.F., Ettler V., "Fluids are bound to be involved in the formation of ophiolitic chromite deposits", Eur, J, Mineral.(2017).
[24] Salehi S., "Petrography and geochemistry of ultrabasic rocks of Grom Rudan mountain, Master's thesis,Hormozgan university (In Persian)", (2015) 160p.
[25] Sabzehi M., "Kolān e Masāʾel Ophiolit ha ye Iran", [Comprehensive issues of ophiolites of Iran]. Tehran: Iranian Geological Survey (1994).
[26] Saccani E., Delavari M., Dolati A., Marroni M., Pandolfi L., Chiari M., Barbero E., "New insights into the geodynamics of Neo-Tethys in the Makran area: Evidence from age and petrology of ophiolites from the Coloured Mélange Complex (SE Iran)”, Gondwana Res. 62, (2018) 306–327. https://doi.org/10.1016/j.gr.2017.07.013.
[27] Delavari M., Dolati A., Marroni M., Pandolfi L., Saccani E., "Association of MORB and SSZ ophiolites along the shear zone between Coloured Mélange and Bajgan Complexes (North Maran, Iran): Evidence from the Sorkhband area", Ofioliti 41, (2016) 21–34.
[28] Barbero E., Pandolfi L., Delavari M., Dolati A., Saccani E., Catanzariti R., Lucani V., Chiari M., Marroni M., " The western Durkan Complex (Makran Accretionary Prism,SE Iran): A Late Cretaceous tectonically disrupted seamounts chain and its role in controlling deformation style", Geosci. Front. 12, (2021 )101106. https://doi.org/10.1016/j.gsf.2020.12.001.
[29] Saccani E., Delavari M., Dolati A., Pandolfi L., Barbero E., Tassinari R., Marroni M., "Geochemistry of basaltic blueschists from the Deyader Metamorphic Complex (Makran Accretionary Prism, SE Iran): New constraints for magma generation in the Makran sector of the Neo-Tethys", J. Asian Earth Sci. 228 (2022), 105141,https://doi.org/10.1016/j.jseaes.2022.105141.
[30] Burg J.P., "Geology of the onshore Makran accretionary wedge: Synthesis and tectonic interpretation", Earth-Sci. Rev. 185,( 2018) 1210–1231. https://doi.org/10.1016/j.earscirev.2018.09.011.
[31] McCall G. J. H, "A summary of the geology of the Iranian Makran", In P. D. Clift, F. D. Kroon, C. Gaedecke, & J. Craig (Eds.), The tectonic and climatic evolution of the Arabian Sea region (Geological Society, London, Special Publication No. 195, pp. (2002) 147–204. Geological Society of London.
https://doi.org/10.1144/GSL.SP.2002.195.01.10.
[32] McCall G. g. H., Morgan K. H., Huber H., "Geological Quadrangle Map of Minab", 1:250,000 Series, Sheet J13,. Geol. Surv. Iran. Tehran (1983).
[33] Streckeisen A., "Classification and nomenclature of volcanic rocks, lamprophyres,carbonatites, and melilitic rocks:recommendation and suggestion of the IUGS subcommission on the systematic of Igneous Rock", Geology, 7(7), (1979) 331–335.
 
 
 
[34] Le Bas M.J., "IUGS Reclassification of the High-Mg and Picritic Volcanic Rocks", Journal of Petrology, 41(10), (2000) 1467–1470.
[35] Guilbert J.M., Park C.F. Jr., "The geology of ore deposits", Freeman publication, USA, (1985) 985 pp.
[36] Duke J. M., "Magmatic segregation deposits, in Roberts, R. G. and Sheahan, P. A. (eds.), ore deposit models", Geoscience Canada, Reprint Series 3(1988) 133-143.
[37] Masoudi J., Imamalipour A., "Application of geological methods for prospecting podiform chromite deposits in the Khoy ophiolite zone, northwestern Iran(In Persian)", Economic Geology, 11(2) (2019) 285–303. https://doi.org/10.22067/econg.v11i2.70623.
[38] Shayestefar M. R., Mohammadi M., Rezaei A., "Application of geological methods in the exploration of podiform chromite deposits in the Khoy ophiolite zone, NW Iran (In Persian)", Journal of Economic Geology, 1(3) (2008) 29–40.
[39] Jahanshahi M., Dorvishzadeh L., "Metamorphic evolution of parental magma and genesis of chromites at Cheshmeh Bid Neyriz ophiolite (In Persian)", Fars Province, Iran. Iranian Journal of Crystallography and Mineralogy, (2023) 31(1).
[40] Veisinia A., Ebrahimi M., Mokhtari M., Ahmadian J., Azimzadeh A., "Application of Cr spinel mineral chemistry in petrogenetic evolution and tectonic setting of NE Kamyaran ophiolitic complex", Iranian Journal of Crystallography and Mineralogy, 26 (3) (2018) 581-596.
[41] Zhou M. F., Robinson P. T., Bai W., "Formation of Podiform Chromitites by melt/rock interaction in the upper Mantle", V29 (1994) pp.98-101.
[42] Irvine T.N., "Origin of chromitite layers in the Muskox intrusion and other stratiform intrusions: A new interpretation", Geology(1977), 5, 273.
[43] Pearce J.A., Lippard S.J., Roberts S., "Characteristics and tectonic significance of Suprasubduction Zone Ophiolites", Geol. Soc, Lond Spec. Publ., (1984) 16,77-94. https://doi.org/10.1144/GSL.SP.1984.016.01.06.
[44] Jannesari G., Shafaii Moghadam H., Peighambari S., "Geochemistry and petrogenesis of the Late Cretaceous Haji‑Abad ophiolite (Outer Zagros Ophiolite Belt, Iran): implications for geodynamics of the Bitlis–Zagros suture zone". Geological Journal, 48(6), (2013) 579–602. https://doi.org/10.1002/gj.2458.