Mineralogy, geochemistry, and textural analysis of Galumak perlitic-spherulitic rocks, southwest of Kerman: Evidence of devitrification processes in non-marine environment

Document Type : Original Article

Authors

Shahid Bahonar University of Kerman

Abstract

The Miocene perlitic-spherulitic rocks of Galumak, located in the southern part of Urumieh-Dokhtar magmatic assemblage, are characterized by the presence of phenocrysts such as plagioclase, biotite, clinopyroxene, and amphibole. These rocks exhibit various textures resulting from devitrification processes, which are influenced by temperature variations and the presence of fluids. At the highest temperatures, perlitic textures are formed during rapid hydration and expansion processes. As the temperature decreases, a range of features emerges, including lithophysae, isolated spherulites, and clustered spherulites. Ultimately, the growth of fibrous crystals and the development of banded flow textures are observed at the lowest temperatures. All these textures contribute to the progressive development of cryptocrystalline to microcrystalline textures, accompanied by the gradual elimination of glass. X-ray diffraction (XRD) analysis confirms the presence of minerals such as plagioclase, K-feldspar, cristobalite, and diopside in these rocks. Geochemical studies reveal that these rocks exhibit a rhyolitic composition, classified as subalkaline, and display a metaluminous nature. It is inferred that the studied rocks have similar origin and occurred during the hydration and devitrification processes of pyroclastic flows in a non-marine environment. Notably, the chemical composition of these rocks is comparable to other industrial perlite deposits worldwide.

Keywords


[1] Davis B., Mcphie J., "Spherulite, quench fractures, and relict perlite in a late Devonian rhyolite dyke", Journal of Volcanology and Geothermal Research 71 (1996) 1-11.
[2] Fazlnia A., Pang K., Ji W., Pirouei M., "Geochemical constraints on Eocene ignimbrite flare-up in the Urumieh-Dokhtar magmatic arc, northwestern Iran", Lithos 450-451 (2023) 107189.
[3] Saraby F., "Igneous petrology (in Persian)", University of Tehran (2006) 317 p.
[4] Zheng H., Sun X., Wang J., Zhu D., Zhang X., "Devitrification pores and their contribution to volcanic reservoirs: A case study in the Hailar Basin, NE China", Marine and Petroleum Geology 98 (2018) 718-732.
[5] Hanson S. L., "Word to the Wise: Spherulites and Lithophysae", Rocks & Minerals 95 (2020) 183-187.
[6] Dimitrijevic M.D., "Geology of Kerman Region", Geology Survey of Iran, Report No. 52 (1973) 334 p.
[7] Mohajjel M., Sahandi R., "The tectonic evolution of the Sanandaj-Sirjan zone in the north-western half and the introduction of a new sub-zone in it (in Persian)", Journal of Earth Sciences 8 (1993) No. 31-32.
[8] Srdic A., Dimitrijevic M.N., Cvetic S., "Dimitrijevic M.D., Geological map of Iran, Scale 1:100000 Series Bardsir", Tehran Naqsheh (1992).
[9] Zarei S., "Petrography, Geochemistry, and Petrogenesis of Galumak Upper Oligocene Perlitic rocks, Southwest of Kerman (in Persian)", M.Sc. Thesis, Shahid Bahonar University of Kerman (2015) 131 p.
[10] William H., Turner F., Gilbert C.H., “Petrography”, W.H. Freeman, (1982) 552 p.
[11] Szepesi J., Lukács R., Soós I., Benkó Z., Pécskay Z., Ésik Z., Kozák M., Di Capua A., Groppelli G., Norin G., Sulpizio R., Harangi S., "Telkibánya lava domes: Lithofacies architecture of a Miocene rhyolitefield (Tokaj Mountains, Carpathian-Pannonian region, Hungary", MTA-ELTE Volcanology Research Group, Budapest, Hungary 385 (2019) 179–197. )doi.org/10.1016/j.jvolgeores.2019.07.002(
[12] De Rita D., Giordano G., Cecili A., "A model for sub-marine rhyolite dome growth: Ponza Island (central Italy", Journal of Volcanology and Geothermal Research 107 (2001) 221–239.
[13] Németh K., Pécskay Z., Martin U., Gméling K., Molnár F., Cronin S.J., "Hyaloclastites, peperites and soft-sediment deformation textures of a shallowsubaquaeous Miocene rhyolitic dome cryptodome complex, Pálháza, Hungary", Geological Society special publication 302 (2008) 63–86. )doi.org/10.1144/sp302.5(
[14] Porreca M., Cifelli F., Soriano C., Giordano G., Romano C., Conticelli S., Mattei M., "Hyaloclastite fragmentation below the glass transition: An example from El Barronal submarine volcanic complex (Spain) ", Geology 42 (2014) 87–90. )doi.org/10.1130/G34744.1.(
[15] Tuffen H., Castro J., "The emplacement of an obsidian dyke through thin ice: Hrafntinnuhryggur, Krafla Iceland", Journal of Volcanology and Geothermal Research 185 (2009) 352–366. )doi.org/10.1016/B978-0-12-409548-9.12527-8(.
[16] Ellis B.S., Bachmann O., Wolff J.A., "Cumulate fragments in silicic ignimbrites: the case of the Snaken River Plain", Geology 42 (2014) 431–434.
[17] Allen R.L., Schofield M., Sparkes G.W., "Volcanic-facies mapping and related hydrothermal alteration studies of the Buchans Camp, Southern Buchans–Roberts Arm Belt, Central Newfoundland", Newfoundland and Labrador Department of Industry, Energy and Technology, Geological Survey, Report 24-1 (2024) 1-30 pp.
[18] Vernon R.H., "A practical guide to rock microstructure", Cambridge University (2004) 594 p. (doi.org/10.1017/CBO9780511807206).
[19] Öztürk Y.Y., Akal C., "The First Petrographic Textural Data of Sferulitic Rhyolites Observed in the west of İdrisyayla (Kırka-Eskişehir) ", Geological Bulletin of Turkey 66 (2023) 59-74.
[20] Riehle J.R., "Relations between thermal history and secondary structures of ignimbrites exclusive of rheomorphism", Geosphere11 (2015) 572-605. 
[21] Howoeth H.H., "The Recent Elevation of the Himalayas", Geological Magazine 9 (1892) 276-278.
[22] Breitkreuz C., "Spherulites and lithophysae—200 years of investigation on high-temperature crystallization domains in silica-rich volcanic rock", Bulletin of Volcanology 75 (2013) 705 p. (doi:10.1007/s00445-013-0705-6).
[23] Befus K.S., Watkins J., Gardner J.E., Richard D., Befus, K.M, Miller N.R., Dingwell D.B., "Spherulites as in-situ recorders of thermal history in lava flows", Geology 43 (2015) 647-650.
[24] Marshall R.R., "Devitrification of natural glass", Journal of Geological Society of America Bulletin 72 (1961) 1493-1520.
[25] Lofgren G., "Experimental devitrification rate of rhyolite glass", Journal of Geological Society of America Bulletin 81 (1970) 553-560.
[26] Lofgren G ., "Experimentally produced devitrification rate texture in natural rhyolitic glass", Journal of Geological Society of America Bulletin 82 (1971) 111-124. (doi: 10.1130/0016-7606)
[27] Lofgern G., "Experimentally produced devitrification textures in natural Rhyolitic glass", Geological Society of American Bulletin 82 (1974) 111- 124.
[28] Ali A., Chiang Y.W., Santos R.M., "X-ray Diffraction Techniques for Mineral Characterization: A Review for Engineers of the Fundamentals, Applications, and Research Directions", Minerals 12 (2022) 205. (doi.org/10.3390/min12020205).
[29] Sharma R., Bisen D.P., Shukla U., Sharma B.G., "X-ray diffraction: A powerful method of characterizing nanomaterials", Journal of The Recent Research in Science and Technology 4 (2012) 77–79.
[30] Al-Mashaikie S.Z.A.K., Al-Hawbanie A.M., "Petrography and Geochemical Study of the Perlite Rocks from Bait Al-Qeyarie, Kawlan Area, Yemen", Journal of King Abdulaziz University-Earth Sciences 21(2) (2010) 195-217.
[31] Mathers S.J., Harrison D.J., Mitchell C.J., Evans E.J., "Exploration, Evaluation and Testing of Volcanic Raw Materials for Use in Construction", British Geological Survey (2000) 116 p.
[32] Elzea Kogel J., Trivedi N.C., Barker J.M., Krukowski S.T., "Industrial Minerals and Rocks, Commodities, Markets and Uses", Society for Mining, Metallurgy and Exploration Inc (SEM), Littleton, Colorado, USA (2006) 685-702.
[33] Angelopoulos P.M., "Insights in the Physicochemical and Mechanical Properties and Characterization Methodology of Perlites", Minerals 14 (2024) 113. (https://doi.org/10.3390/min14010113).
[34] Le Bas M.J., Le Maitre R.W., Strekeisen A., Zanettin B., "A chemical classification of volcanic rocks based on the total alkali–silica diagram", Journal of Petrology 27 (1986) 745-750.
[35] Rickwood P.C., "Boundry lines within petrologic diagrams which use oxides of major and minor elements", Lithos 22 (1989) 247-263.
[36] Chatterjee K.K., "Uses of Industrial Minerals, Rocks and Freshwater" Nova Science: New York, NY, USA 53 (2013).
[37] Shand S.J., "Eruptive rock", Thomas Murby and Company, London (1947) 236 p.