Synthesis and structural characterization of cobalt (II) complex with Schiff base ligand encapsulated in Zeolite ZMS-5

Document Type : Original Article

Authors

1 Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

2 Department of Chemistry, Qom Branch, Islamic Azad University, Qom, Iran

3 Department of Biomedical Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran

Abstract

In this research, zeolite ZMS-5 was synthesized by hydrothermal method and ion-exchanging of Na+ with Co2+ within the zeolite was occurred. Schiff- base ligand (L) (L= 6,6'-((1E,1'E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)) was prepared with the reaction of 2-Hydroxy-3-methoxybenzaldehyde  and ethylenediamine. The flexible ligand (FL) method was used for the capsulated of complex into of the zeolite cage. The structure of capsulated zeolite with Co-L complex was characterized by FT-IR and XRD, and the size and morphology of compound was determined with SEM. 

Keywords

References

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History

  • Receive Date: 22 July 2024
  • Revise Date: 03 September 2024
  • Accept Date: 25 September 2024

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