اثر مقدار حلال بر ساخت NiCo-ZIF و MgCo-ZIF با استفاده از چارچوب فلزی-آلی ZIF-67

نویسندگان

1 آزمایشگاه تحقیقاتی انرژی‌های تجدیدپذیر، مغناطیس و نانوفناوری، گروه فیزیک دانشگاه فردوسی مشهد، مشهد، ایران.

2 گروه فیزیک دانشکده علوم، دانشگاه فردوسی مشهد، مشهد، ایران.

3 شرکت آتی کاوان انرژی پارت، گروه پارت لاستیک، شهرک صنعتی فناوری‌های برتر، مشهد، ایران.

چکیده

در این پژوهش، دو بلورNiCo-ZIF  و MgCo-ZIF با افزودن عناصر نیکل و منیزیم به چارچوب­ فلزی-آلی ایمیدازولات زئولیتی ZIF-67، به روش حلال­گرمایی در دمای اتاق و با مقادیر مختلف 50، 100 و 150 میلی­لیتر از حلال متانول تهیه شدند. اثر مقدار حلال بر ساختار، اندازه ذره و ریخت­شناسی نمونه­ها با روش‌های مختلف مشخصه­یابی بررسی شد. تحلیل پراش پرتو ایکس نشان داد که با افزایش مقدار حلال از 50 به 100 میلی­لیتر، شدت قلّه­ها کاهش و با 150 میلی­لیتر، شدت قلّه­ها افزایش می­یابد. این روند ناشی از تغییر در بلورینگی ذرات به علت رقیق شدن محیط واکنش از یک سو و افزایش سرعت هسته­زایی از سوی دیگر است. بر پایه تصاویر میکروسکوپ الکترونی روبشی گسیل میدانی (FESEM) از نمونه­های­ NiCo-ZIF تهیه شده  50، 100 و 150 میلی­لیتر با حلال، میانگین اندازه ذرات به ترتیب از 845 به 550 و 391 نانومتر کاهش می­یابد. این رفتار کاهشی برای نمونه­های­ MgCo-ZIF با مقادیر 656، 411 و 299 نانومتر به دست آمد. علت این امر، افزایش تعداد مکان­های فعال در مرحله هسته­زایی بلور است. نتایج طیف­سنجی های پراکندگی انرژی بلوری پرتوی X (EDX) و تبدیل فوریه فروسرخ (FTIR) نشان داد که قابلیت اتصال متفاوت یون­های فلزی Co2+،Ni2+  و  Mg2+به لیگاند آلی، باعث تفاوت مقدار این عناصر در نمونه­ها می­شود. نتیجه این پژوهش نشان می­دهد که مقدار حلال یکی از عوامل مهم در ساخت بلورهای ZIF است که کنترل آن می­تواند به دستیابی به ذرات با اندازه و ریخت­شناسی مطلوب کمک کند.

کلیدواژه‌ها

عنوان مقاله [English]

Effect of Solvent Amount on Synthesis of NiCo-ZIF and MgCo-ZIF Using the Metal-Organic Framework, ZIF-67.

نویسندگان [English]

  • Fatemeh shekofte 1
  • Hadi Arabi 1
  • Shaban Reza Ghorbani 2
  • Nasrin Azad 3
1 Research Laboratory of Renewable Energy, Magnetism and Nanotechnology, Department of Physics, Ferdowsi University of Mashhad, Mashhad, Iran.
2 Department of Physics, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran.
3 Ati Kavan Energy Part Company, Rubber Part Group, Top Technologies Industrial Estate, Mashhad, Iran.
چکیده [English]

In this research, two NiCo-ZIF and MgCo-ZIF crystals were prepared by adding nickel and magnesium elements to the ZIF-67 metal-organic framework. The preparation route was performed by solvothermal method at room temperature using different amounts of methanol solvent, 50, 100, and 150 ml. Effect of the amount of solvent on the structure, particle size, and morphology of the samples was investigated by various characterization methods. X-ray diffraction analysis showed that the intensity of the peaks decreases with increasing the amount of solvent from 50 to 100 ml, while at 150 ml, the intensity of the peaks increases. This variation in the peak intensities and consequently particle crystallinity is due to the dilution of the reaction medium on one side and the increase in nucleation rate on the other side. The FESEM images of the NiCo-ZIF sample, prepared at 50, 100 and 150 ml solvent, indicate that the average particle size reduces from 845 to 550 and 391 nm, respectively. The unique reduction behavior was obtained for the MgCo-ZIF sample with values of 656, 411, and 299 nm, respectively. This is due to the increasing number of active sites in the crystal nucleation stage. The results of EDX and FTIR indicated that the fact of different binding ability of metal ions Co2+, Ni2+, and Mg2+ to the organic ligands causes the difference in the amount of these elements in the samples. The outcome of this study shows that the amount of solvent is one of the essential factors in the synthesis of ZIF crystals, whose control can help to obtain particles with the desired size and morphology.

کلیدواژه‌ها [English]

  • metal-organic frameworks
  • Zeolite Imidazolate Frameworks
  • ZIF-67
  • Solvent Amount
  • particle size
  • morphology

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سابقه مقاله

  • تاریخ دریافت: 01 خرداد 1403
  • تاریخ بازنگری: 18 تیر 1403
  • تاریخ پذیرش: 27 تیر 1403

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