اثر جانشانی‌های هم‌زمان نیکل و روی بر ویژگی‌های ساختاری، نوری و فوتوکاتالیزوری فریت Cu1-3xNixZn2xFe2O4

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشکده فیزیک، دانشگاه دامغان، دامغان، ایران

چکیده

در این کار، ویژگی­های ­ساختاری، نوری و فوتوکاتالیزوری فریت­های Cu1-3xNixZn2xFe2O4  تهیه شده به روش سیترات نیترات بررسی شد. نمونه­ها به­ روش­­های پراش پرتو ایکس (XRD)، و طیف‌سنجی فرابنفش-مرئی UV-Vis در دمای اتاق مشخصه­یابی شدند. الگوهای XRD گویای یک گذار فاز ساختاری اسپینلی از فاز چارگوشی به مکعبی و یک افزایش تقارن با جانشانی همزمان نیکل و روی در فریت مس هستند. مقادیر گاف نواری  نمونه­ها یک مقدار کمینه eV 43/1 را با 05/0 x = نشان می­دهد. بیشترین فعالیت کاتالیزوری 95 درصد در تخریب متیلن بلو با نمونه 05/0 x = به دلیل کوچکتر بودن گاف انرژی بدست آمد. 

کلیدواژه‌ها

عنوان مقاله [English]

Effect of Ni and Zn co-substitutions on structural, optical, and photocatalytic properties of Cu1-3xNixZn2xFe2O4 ferrite

نویسندگان [English]

  • Fahimeh Takalloo
  • Ahmad Gholizadeh
  • Mahdi Ardyanian
School of Physics, Damghan University, Damghan, Iran
چکیده [English]

In this work, the structural, optical and photocatalytic properties of Cu1-3xNixZn2xFe2O4 ferrites prepared by citrate-nitrate method were investigated. The samples were characterized by X-ray diffraction (XRD) and UV-Vis spectrometer at room temperature. Examining the XRD patterns indicates the presence of a spinel structural phase transition from a tetragonal to cubic structure, which shows an increase in symmetry with the co-substitution of Ni and Zn in the copper ferrite. The bandgap values of the samples show a minimum value of 1.43 eV for x = 0.05. The highest catalytic activity of 95% in the degradation of methylene blue is obtained for the x = 0.05 sample due to its smaller energy gap.

کلیدواژه‌ها [English]

  • Cu spinel ferrite
  • Nitrate citrate method
  • Substitution effect
  • Optical properties
  • photocatalytic activity

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  • تاریخ دریافت: 10 آبان 1402
  • تاریخ بازنگری: 21 آذر 1402
  • تاریخ پذیرش: 16 دی 1402

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