سنتز و بررسی ساختار بلوری ترکیب سوپرامولکولی هسته-پوسته از نانوخوشه پلی-اکسووانادات

نوع مقاله : مقاله پژوهشی

نویسندگان

گروه شیمی معدنی، دانشکده شیمی، دانشکدگان علوم، دانشگاه تهران، تهران، ایران

چکیده

ترکیب سوپرامولکولی از وانادیوم (V) با فرمول [حلال+] [(CH3)2NH2]4[V16O42](SO4).2(O) (ترکیب 1) در سامانه­ بلوری چارگوشی، گروه فضایی P < /span>42/nnm با دو مولکول در هر یاخته یکه (2Z=)  متبلور شد. مقدار R نهایی ترکیب 1 برای 2214 بازتاب مستقل برابر با ۰48/۰ است. واحد بی­تقارنی این ترکیب شامل نیمی از کاتیون دی‌متیل‌آمونیوم، یک چهارم آنیون سولفات، بخشی از خوشه وانادیوم و مولکول­های آب است. در ساختار سوپرامولکولی ترکیب 1، هر کاتیون دی‌متیل‌آمونیوم از طریق پیوندهای هیدروژنی بین دو خوشه پلی‌اکسووانادات پل شده­ است و آنیون‌های سولفات نقشی کلیدی دارند، زیرا ساختار سوپرامولکولی چارگوشی در راستای این آنیون­ها گسترش می‌یابد.    

کلیدواژه‌ها

عنوان مقاله [English]

Synthesis and crystal structure of core-shell supramolecular compound of polyoxyvanadate nanoclusters

نویسندگان [English]

  • Faezeh Moghzi
  • Farnam Zamani Foroushani
  • Janet Soleimannejad
School of Chemistry, College of Science, University of Tehran, P.O. Box 14155 6455, Tehran, Iran
چکیده [English]

A supramolecular compound of vanadium (V) with [(CH3)2NH2]4[V16O42](SO4).2(O)[+solvent] formula (1) was crystallized in the tetragonal crystal system, space group P42/nnm with Z=2. The final R value of compound 1 is 0.048 for 2214 independent reflections. The asymmetric unit of 1 consists of a half of the dimethylammonium cation, a quarter of sulfate anion, a part of vanadium cluster, and water molecules. In the supramolecular structure of compound 1, each dimethyl ammonium cation is bridged between two polyoxovanadate clusters through hydrogen bonds and sulfate anions play a key role as the tetragonal supramolecular structure extends along these anions.

کلیدواژه‌ها [English]

  • Supramolecular chemistry
  • Vanadium
  • Polyoxovanadate
  • crystal structure

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سابقه مقاله

  • تاریخ دریافت: 19 فروردین 1402
  • تاریخ بازنگری: 26 خرداد 1402
  • تاریخ پذیرش: 10 تیر 1402

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