تهیه، شناسایی و بررسی ساختار بلوری کمپلکس مس دو ظرفیتی با لیگاند جدید 3،ʹ3،ʺ3،ʺʹ3-(پروپان-2،1-دی‌ایل‌بیس(آزانیتریل)) اسید تتراپروپانوئیک‌

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه شیمی، دانشکده علوم پایه، دانشگاه پیام نور، تهران، ایران.

2 گروه شیمی، دانشکده علوم پایه، دانشگاه پیام نور، تهران، ایران.نور

چکیده

در این پژوهش، ترکیب جدید تترامتیل-3،ʹ3،ʺ3،ʺʹ3-(پروپان-2،1-دی‌ایل‌بیس(آزانیتریل))تتراپروپیونات (TPAT) از واکنش پروپان-2،1-دی‌آمین و متیل‌آکریلات در حلال متانول تهیه گردید. ترکیب TPAT در محیط بازی، همزمان با تشکیل کمپلکس به لیگاند 3،ʹ3،ʺ3،ʺʹ3-(پروپان-1،2-دی‌ایل‌بیس(آزانیتریل)) ‌اسید تتراپروپانوئیک (H4PAT) تبدیل شد. کمپلکس 3،ʹ3،ʺ3،ʺʹ3-(پروپان-2،1-دی‌ایل‌بیس(آزانیتریل))تتراپروپیونات‌مس‌(II) [Cu(H2PAT)] با روش‌های طیف‌سنجی تبدیل فوریه فروسرخ (FT-IR)، تشدید مغناطیسی هسته­ای پروتون (HNMR) و تجزیه عنصری کربن، هیدروژن، نیتروژن و گوگرد (CHNS) شناسایی و با پراش پرتوی X (XRD) تعیین ساختار گردید. لیگاند H4PAT از طریق دو اتم نیتروژن، دو اتم اکسیژن از یون پروپیونات و یک گروه کربونیل از ‌اسید پروپانوئیک به اتم مس همتافته شده است و آرایش هندسی هرم مربعی واپیچیده دارد. این کمپلکس در سیستم بلوری راستگوشی با گروه فضایی Pna21 با  Å a=14.1429(8) ، Å b=14.1429(8) و Å  c=9.9781(3)با چهار مولکول در یاخته یکه (Z=4) متبلور شده است. کاربرد کاتالیزوری این کمپلکس بررسی شد. از 2 میلی ‌مول کمپلکس [Cu(H2PAT)] برای جفت شدن فنیل برمید، در شرایط تقطیر، بدون حلال در مدت زمان 120 دقیقه استفاده شد و بی‌فنیل با بازده 80 درصد تشکیل گردید.

کلیدواژه‌ها

عنوان مقاله [English]

Preparation, identification and investigation of the crystal structure of bivalent copper complex with new ligand 3,3ʹ,3ʺ,3ʺʹ-(propane-1,2-diylbis(azanetriyl))tetrapropanoic acid

نویسندگان [English]

  • Nourmohamadzadeh 1
  • Hakimi 2
  • Hassani 2
1 Inorganic Chemistry, Faculty of Chemistry, Payam Noor University, Tehran, Iran
2 Inorganic Chemistry, Faculty of Chemistry, Payam Noor University, Tehran, Iran
چکیده [English]

In this research, a new compound of tetramethyl-3,3ʹ,3ʺ,3ʺʹ-(propane-1,2-diylbis(azanetriyl))tetrapropionate (TPAT) was prepared from the reaction of propane-1,2-diamine and methyl acrylate in methanol solvent. The composition of TPAT in the base environment, simultaneously with the formation of the complex, was reaction to the ligand 3,3ʹ,3ʺ,3ʺʹ-(propane-1,2-diylbis(azanetriyl))tetrapropanoic acid (H4PAT). 3,3ʹ,3ʺ,3ʺʹ-(propane-1,2-diylbis(azanetriyl))tetrapropionate copper(II) complex [Cu(H2PAT)] was identified by FT-IR, 1H NMR spectroscopy, elemental analysis (CHN) and its structure was determined by X-ray single crystal. H4PAT ligand is coordinated to copper atom through two nitrogen atoms, two oxygen atoms from propionate ion and one carbonyl group from propanoic acid and has a distorted square pyramidal geometry. This complex is crystallized in orthorhombic crystal system with space group Pna21 and Z=4 with a=14.1429(8) Å, b=14.1429(8) Å and c=9.9781(3) Å. The catalytic application of this complex was investigated. 2 mmol of [Cu(H2PAT)] complex was used for the coupling of phenyl bromide, under reflux conditions, without solvent in 120 minutes, and the biphenyl product was formed with 80% efficiency.

کلیدواژه‌ها [English]

  • propane-1
  • 2-diamine derivatives
  • polydentate ligand complex
  • copper(II) complex
  • crystal structure
  • coordination chemistry

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  • تاریخ دریافت: 01 اسفند 1401
  • تاریخ بازنگری: 24 اسفند 1401
  • تاریخ پذیرش: 16 فروردین 1402

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