Crystal Structure of Trimetallic 3D-dimensional Coordination Polymer from Cadmium, Magnesium and Sodium with Benzene-1,2,4,5-tetracarboxylic Acid

Document Type : Original Article

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Abstract

The reaction of magnesium chloride and cadmium nitrate with benzene-1,2,4,5-tetracarboxylic acid in the presence of NaOH and in aqueous solution led to formation of 3-dimensional coordination polymer formulated as, [Cd(bta)Na(H2O)4Mg0.5].2H2O}n(1) (btaH4 = benzene-1,2,4,5-tetracarboxylic acid),. The crystal structure of 1 was determined by X-ray diffraction. The Single-crystal X-ray structure shows that the asymmetric unit of 1 consists of cadmium, sodium and magnesium in (1:1:0.5) ratio. Three metals cations are linked with oxygen atoms of benzene-1,2,4,5-tetracarboxylate.  Benzene-1,2,4,5-tetracarboxylate acts as bidentate and monodentate bridging ligand and causes to making trimetallic 3-dimentinal coordination polymer.
 

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References

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History

  • Receive Date: 26 September 2021
  • Revise Date: 11 November 2021
  • Accept Date: 24 November 2021

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