ساختار بلوری پلیمر هم آرای سه فلزی سه بعدی از کادمیم، منیزیم و سدیم با بنزن 1 و 2 و 4و 5- اسید تترا کربوکسیلیک

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه آزاد اسلامی، واحد یزد

چکیده

از واکنش کلرید منیزیم، نیترات کادمیم با اسید (bata) بنزن-1و2و3و4 تتراکربوکسیلیک در حلال آب و در جضور NaOH ، کمپلکس پلیمری با فرمول {[Cd(bta)Na(H2O)4Mg0.5].2H2O}n (1) تهیه شد. ساختار بلوری کمپلکس با پراش پرتوی X تعین شد. نتایج نشان می­دهد که هر واحد بیتقارن این پلیمر هم آرا شامل کادمیم (II)، سدیم و منیزیم با نسبت مولی 1 : 1: 5/0 است. سه کاتیون فلزی با اکسیژن­های بنزن- 1و2و4و5- کربوکسیلات به هم وصل شده­اند. بنزن- 1و2و4و5- کربوکسیلات هم به صورت دو دندانه و هم یک دندانه به کاتیون­های فلزی متصل شده و پلیمر هم آرای سه بعدی با سه فلز مختلف را ایجاد کرده است.

کلیدواژه‌ها

عنوان مقاله [English]

Crystal Structure of Trimetallic 3D-dimensional Coordination Polymer from Cadmium, Magnesium and Sodium with Benzene-1,2,4,5-tetracarboxylic Acid

نویسندگان [English]

  • Mohammadi
  • Tabatabaee
  • Mohebat
چکیده [English]

The reaction of magnesium chloride and cadmium nitrate with benzene-1,2,4,5-tetracarboxylic acid in the presence of NaOH and in aqueous solution led to formation of 3-dimensional coordination polymer formulated as, [Cd(bta)Na(H2O)4Mg0.5].2H2O}n(1) (btaH4 = benzene-1,2,4,5-tetracarboxylic acid),. The crystal structure of 1 was determined by X-ray diffraction. The Single-crystal X-ray structure shows that the asymmetric unit of 1 consists of cadmium, sodium and magnesium in (1:1:0.5) ratio. Three metals cations are linked with oxygen atoms of benzene-1,2,4,5-tetracarboxylate.  Benzene-1,2,4,5-tetracarboxylate acts as bidentate and monodentate bridging ligand and causes to making trimetallic 3-dimentinal coordination polymer.
 

کلیدواژه‌ها [English]

  • Trimetallic complex
  • Coordination polymer
  • Benzene-1
  • 2
  • 4
  • 5-tetracarboxylic acid

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سابقه مقاله

  • تاریخ دریافت: 04 مهر 1400
  • تاریخ بازنگری: 20 آبان 1400
  • تاریخ پذیرش: 03 آذر 1400

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