Synthesis, identification and determination of the crystal structure of a New Copper (II) Complex Based on Schiff's tetradentate Ligand of Pyridine and 1,6-Diamino-3-Azaxane

[1] Karadag A., Bulut A., Buyukgungor O., "trans-Bis‌[N-(2-hy‌droxy‌ethyl)‌ethyl‌ene‌diamine-κ2N,N′]‌bis‌(iso‌thio‌ cyanato-κN)‌nickel(II) ", Acta Crystallographica Section C 60 (2004) 402–404.

[2] Wade P.W., Hancock R.D., "Metal Ion Size Selectivity in Ligands with Groups Containing the Neutral Oxygen Donor Atom. A Crystallographic and Thermodynamic Study", Inorganica Chimica Acta 130 (1987) 251–257.

[3] Azadbakht R., Rudbari H.A.,‌ Bruno G., "Bis[2-(2-aminoethylamino)ethanol] copper(II) Dinitrate", Acta Crystallographica Section E 67 (2011) m 1230.

[4] Odoko M., Kusano A., Oya N., Okabe N., "A lithium complex of pyridine-2,6-dicarboxylic acid", Acta Crystallographica Section C 58 (2002) m215- m216.

[5] Galanski M., Zimmermann W., Berger M., Baumgartner C., Giester G., Keppler B.K., "Carboxylation of 2-Hydroxyethyl-Substituted Tetrachloro(ethane-1,2-diamine)platinum(IV) Complexes — A New Synthetic Approach to Anticancer Platinum Compounds", European Journal of Inorganic Chemistry (2001) 417–421.

[6] Song Y. F., Abbas H., Ritchie C., McMillian N., Long D. L., Gadegaard N., Cronin L., "From Polyoxometalate Building Blocks to Polymers andMaterials: The Silver Connection", Journal of Materials Chemistry 17 (2007) 1903–1908.

[7] Zhang Y. C., "Synthesis, Crystal Structure, and Fluorescent Property of a Zn(II) Complex with N-Nicotinoylglycine Ligand", Crystals, 7 (2017) 151-158.

[8] Garcia-Tojal J., Garcia-Orad A., Serra J.L., Pizarro J.L., Lezama L., Arriortua M.I., Rojo T., "Biological activity of complexes derived from pyridine-2-carbaldehyde thiosemicarbazone Structure of [Co(C7H7N4S)2][NCS] ", Journal of Inorganic Biochemistry 84 (2001) 271-287.

[9] Hakimi M., Moeini K., Mardani Z., Takjoo R., "Synthesis and Spectral Study of a Copper(I) Complex, [Cu(L)(PPh3)2], with NS-Donor Ligand", Phosphorus, Sulfur, and Silicon and the Related Elements 189 (2014) 596-605.

[10] West D.X., Swearingen J.K., Romack T.J., Billeh I.S., Jasinski J.P., Li Y., Staples R.J., "Crystal structures of copper(II) complexes of 2-formylpyridine substituted thiosemicarbazones; the first example of a coordinated thiosemicarbazone with a thiol function", Journal of Molecular Structure 570 (2001) 129-136.

[11] Ali M.A., Mirza A.H., Hossain A.M.S., Nazimuddin M., "Synthesis, characterization, antifungal properties and X-ray crystal structures of five- and six-coordinate copper(II) complexes of the 6-methyl-2-formylpyridine(4)N-dimethylthiosemicarbazone", Polyhedron 20 (2001) 1045–1052.

[12] Joseph M., Suni V., Kurup M.R.P., Nethaji M., Kishore A., Bhat S.G., "Structural, spectral and antimicrobial studies of copper (II) complexes of 2-benzoylpyridine N (4)-cyclohexyl thiosemicarbazone", Polyhedron 23 (2004) 3069–3080.

[13] Seena E.B., Kurup M.R.P., "Spectral and structural studies of mono-and binuclear copper (II) complexes of salicylaldehyde N (4)-substituted thiosemicarbazones", Polyhedron (2007) 829–836.

[14] Fostiak L.M., Garcıa I., Swearingen J.K., Bermejo E., Castineiras A., West D.X., "Structural and spectral characterization of transition metal complexes of 2-pyridineformamide N(4)-dimethylthiosemicarbazone", Polyhedron 22 (2003) 83-92.

[15] Hakimi M., Mardani Z., Moeini K., Mohr F., "Coordination behavior of dimethyl pyridine-2, 6-dicarboxylate towards mercury (II), cadmium (II) and chromium (III) in the solid-and gaseous state supported by CSD studies", Polyhedron 102 (2015) 569-577.

[16] CrystalClear-SM Expert 2.0. Tokyo, Japan: Rigaku Corporation, (2014).

[17] Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J. A. K., Puschmann H., "OLEX2: a complete structure solution, refinement and analysis program" Journal of Applied Crystallography 42 (2009) 339–341.

[18] Farrugia L. J., "ORTEP-3 for windows - a version of ORTEP-III with a graphical user interface (GUI) " Journal of Applied Crystallography 30 (1997) 565–578.

[19] Addison A. W., Rao T., Reedjik J., Rijn J. V., Verschoor G.,"Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate", Journal of the Chemical Society, Dalton Transactions (1984) 1349−1358.

[20] Haber V., Fábry J., Petrícek V., "A New Schiff Base Complex: {N-[3-(2-Amino ethyl amino) propyl ]salic ylideneaminato- O,N,N',N''}bromozinc(II)", Acta Crystallographica Section C 51 (1995) 884-887.