بررسی اثر غلظت ال – آلانین به عنوان عامل پوششی بر اندازه، کیفیت ساختاری و ریختارشناسی نانو ذرات KTiOPO4 سنتزشده به روش هم رسوبی

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشکده فنی دختران سمنان، دانشگاه فنی حرفه ای، سمنان، ایران

2 دانشکده فیزیک، دانشگاه سمنان، سمنان، ایران

چکیده

نانو ذرات پتاسیم تیتانیل فسفات (KTiOPO4) یا KTP < /span> به روش هم رسوبی و با استفاده از عامل پوششی ال-آلانین با نسبت­های مولی مختلف سنتز شد. اثر غلظت عامل پوششی بر اندازه، کیفیت ساختاری و ریختار نانو ذرات KTP < /span>، بررسی گردید. پراش پرتو ایکس تشکیل ساختار اورتورومبیک در نانوذرات KTP < /span> را تایید نمود. استفاده از عامل پوششی ال - آلانین منجر به تغییر پارامترهای شبکه و چرخش شبکه بلوری شد. بزرگترین و کوچکترین اندازه دانه با استفاده از عامل پوششی با نسبت­های مولی 1:1 و 3:1 به ترتیب برابر با 2/46 و  nm 5/39 بدست آمدند. کمترین کرنش وارد بر شبکه بلوری برابر با 0012/0 ، برای نسبت مولی 3:1 از عامل پوششی دیده شد. کیفیت ساختاری و ریختار نانو ذرات سنتز شده به ترتیب با استفاده از طیف­سنجی تبدیل فوریه فروسرخ
) (FTIR و میکروسکوپ الکترونی روبشی نشر میدانی ) FE-SEM ( بررسی شدند.   

کلیدواژه‌ها

عنوان مقاله [English]

Study on the effect of L-Alanine concentration as capping agent on size, structural quality and morphology of KTiOPO4 nanoparticles synthesized by Co-precipitation method

نویسندگان [English]

  • Gharibshahian 1
  • Tafreshi 2
1 Department of Electrical and Computer Engineering, Faculty of Narjes Vocational, Technical and Vocational University, Semnan, Iran
2 Faculty of physics, Semnan University, Semnan, Iran
چکیده [English]

KTiOPO4(KTP) nanoparticles were synthesized by co-precipitation method using L-Alanine as capping agent. Different mole ratios of L-Alanine used to study on the effect of capping agent concentration on size, structural quality and morphology of KTP nanoparticles. XRD analysis confirmed the formation of orthorhombic phase of obtained KTP nanoparticles. Using L-Alanine as capping agent results in crystal lattice rotation. Largest and smallest grain size were obtained 46.2nm and 39.5nm by 1:1 and 3:1 mole ratios of capping agent respectively. Lowest lattice strain (0.0012) was observed at 3:1 mole ratio of L-Alanine. Structural quality and morphology of synthesized nanoparticles were studied with FT-IR and FE-SEM analyses.

کلیدواژه‌ها [English]

  • Nanoparticles
  • potassium titanyl phosphate
  • co-precipitation method
  • L-alanine
  • capping agent

مراجع

  1. [1] Malekfar R., Ahmadi G., Cheraghi A., Rohollahnejad J., Sahraiyan F., Khanzadeh M., "Micro-Raman scattering of KTP (KTiOPO4) nanocrystallites synthesized by modified sol-gel Pechini method", Acta Physica Polonica A;(2009)51: 308-312. [DOI:10.1016/j.vibspec.2009.08.004]
  2. [1] Malekfar R., Ahmadi G., Cheraghi A., Rohollahnejad J., Sahraiyan F., Khanzadeh M., "Micro-Raman scattering of KTP (KTiOPO4) nanocrystallites synthesized by modified sol-gel Pechini method", Acta Physica Polonica A;(2009)51: 308-312. [DOI:10.1016/j.vibspec.2009.08.004]
  3. [2] Gharibshahian E., Jafar Tafreshi M., fazli M., "Growth of KTiOPO4 crystals by flux technique and their characterization", Indian J. Pure & Ap. Phy;(2009)47:356-361.
  4. [2] Gharibshahian E., Jafar Tafreshi M., fazli M., "Growth of KTiOPO4 crystals by flux technique and their characterization", Indian J. Pure & Ap. Phy;(2009)47:356-361.
  5. [3] Blessi S., Maria Lumina Sonia M., Vijayalakshmi S., Pauline S., "Preparation and characterization of SnO2 nanoparticles by hydrothermal method", International Journal of ChemTech Research, No.3, (2014), 16: 2153-2155
  6. [3] Blessi S., Maria Lumina Sonia M., Vijayalakshmi S., Pauline S., "Preparation and characterization of SnO2 nanoparticles by hydrothermal method", International Journal of ChemTech Research, No.3, (2014), 16: 2153-2155
  7. [4] Xuan L.L., Chauvat D., Slablab A., Roch J. R., "KTiOPO4 Single Nanocrystal for Second-Harmonic Generation Microscopy", "Nanocrystals", Yoshitake Masuda (Ed.), (2010), ISBN: 978-953-307-126-8
  8. [4] Xuan L.L., Chauvat D., Slablab A., Roch J. R., "KTiOPO4 Single Nanocrystal for Second-Harmonic Generation Microscopy", "Nanocrystals", Yoshitake Masuda (Ed.), (2010), ISBN: 978-953-307-126-8
  9. [5] Abrabri M., Larbot A., Persin M., Sarrazin J., Rafiq M.,Cot L., "Potassium titanyl phosphate membranes : Surface properties and application to ionic solution filtration", J Membr Sci Technol;(1975) 39: 275-283 [DOI:10.1016/S0376-7388(97)00259-7]
  10. [5] Abrabri M., Larbot A., Persin M., Sarrazin J., Rafiq M.,Cot L., "Potassium titanyl phosphate membranes : Surface properties and application to ionic solution filtration", J Membr Sci Technol;(1975) 39: 275-283 [DOI:10.1016/S0376-7388(97)00259-7]
  11. [6] Thuy D., Nguyen T., Lai N.D., "Deterministic Insertion of KTP Nanoparticles into Polymeric Structures for Efficient Second-Harmonic Generation", Crystals; (2019) 9, 365; doi:10.3390/cryst9070365 [DOI:10.3390/cryst9070365]
  12. [6] Thuy D., Nguyen T., Lai N.D., "Deterministic Insertion of KTP Nanoparticles into Polymeric Structures for Efficient Second-Harmonic Generation", Crystals; (2019) 9, 365; doi:10.3390/cryst9070365 [DOI:10.3390/cryst9070365]
  13. [7] Christophe J. B., Mark A. H., George W.S., "Sol-Gel synthesis of Potassium Titanyl Phosphate: Solution Chemistry and Gelation", J. Sol-Gel Sci. Technol.;(1997)9: 183-199. [DOI:10.1007/BF02439398]
  14. [7] Christophe J. B., Mark A. H., George W.S., "Sol-Gel synthesis of Potassium Titanyl Phosphate: Solution Chemistry and Gelation", J. Sol-Gel Sci. Technol.;(1997)9: 183-199. [DOI:10.1007/BF02439398]
  15. [8] Kanno Y., "Synthesis and sintering of KTiOPO4 via mechanochemical mixing route", J ALLOY COMPD; (1994) 210: 45-50. [DOI:10.1016/0925-8388(94)90113-9]
  16. [8] Kanno Y., "Synthesis and sintering of KTiOPO4 via mechanochemical mixing route", J ALLOY COMPD; (1994) 210: 45-50. [DOI:10.1016/0925-8388(94)90113-9]
  17. [9] Arul Dhas N., Patil K.C., "Synthesis of AIPO4, LaPO4 and KTiOPO4 by flash combustion", J ALLOY COMPD;( 1993) 202: 137-141. [DOI:10.1016/0925-8388(93)90532-R]
  18. [9] Arul Dhas N., Patil K.C., "Synthesis of AIPO4, LaPO4 and KTiOPO4 by flash combustion", J ALLOY COMPD;( 1993) 202: 137-141. [DOI:10.1016/0925-8388(93)90532-R]
  19. [10] Kanti Biswas S., Pathak A., Pramanik P., "Synthesis of Nanocrystalline KTiOPO4 Powder by Method", J Am Ceram Soc. ;(2007) 90:1071-1076. [DOI:10.1111/j.1551-2916.2007.01591.x]
  20. [10] Kanti Biswas S., Pathak A., Pramanik P., "Synthesis of Nanocrystalline KTiOPO4 Powder by Method", J Am Ceram Soc. ;(2007) 90:1071-1076. [DOI:10.1111/j.1551-2916.2007.01591.x]
  21. [11] Gharibshahian E., Jafar Tafershi M., Fazli M., "Effects of solution concentration and capping agents on the properties of potassium titanyl phosphate nanoparticles synthesized using a co-precipitation method", J. Phys. Chem. Solids;(2018)116: 241-249 [DOI:10.1016/j.jpcs.2018.01.015]
  22. [11] Gharibshahian E., Jafar Tafershi M., Fazli M., "Effects of solution concentration and capping agents on the properties of potassium titanyl phosphate nanoparticles synthesized using a co-precipitation method", J. Phys. Chem. Solids;(2018)116: 241-249 [DOI:10.1016/j.jpcs.2018.01.015]
  23. [12] Alaei M., Rashidi A. M., Bakhtiari I., "Preparation of High Surface Area ZrO2 Nanoparticles", IJCCE ,No. 2(2014)33: 47-53
  24. [12] Alaei M., Rashidi A. M., Bakhtiari I., "Preparation of High Surface Area ZrO2 Nanoparticles", IJCCE ,No. 2(2014)33: 47-53
  25. [13] Harish K., Manisha and Poonam S., "Synthesis and Characterization of MnO2 Nanoparticles using Co-Precipitation Technique", IJCCE; No. 3;(2013) 3 : 155-160
  26. [13] Harish K., Manisha and Poonam S., "Synthesis and Characterization of MnO2 Nanoparticles using Co-Precipitation Technique", IJCCE; No. 3;(2013) 3 : 155-160
  27. [14] Raquel Serrano-Garcı', Finn Purcell-Milton, Sarah McCarthy, Yurii K. Gun'ko, "Synthesis and Magnetic Properties of L-Alanine Capped CoFe2O4 Nanoparticles", Chemistry Select ;(2018) 3, 4726 - 4729 [DOI:10.1002/slct.201800681]
  28. [14] Raquel Serrano-Garcı', Finn Purcell-Milton, Sarah McCarthy, Yurii K. Gun'ko, "Synthesis and Magnetic Properties of L-Alanine Capped CoFe2O4 Nanoparticles", Chemistry Select ;(2018) 3, 4726 - 4729 [DOI:10.1002/slct.201800681]
  29. [15] Talebi R., "Effect of amino acids as capping agent on the size and morphology of pure TmVO4 nanoparticles and their photocatalyst properties", J Mater Sci: Mater Electron; DOI 10.1007/s10854-016-5648-1
  30. [15] Talebi R., "Effect of amino acids as capping agent on the size and morphology of pure TmVO4 nanoparticles and their photocatalyst properties", J Mater Sci: Mater Electron; DOI 10.1007/s10854-016-5648-1
  31. [16] Indubala E., Dhanasekar M., Sudha V., Padma Malar E.J., Divya P., Jositta Sherine, Revathy Rajagopal, Venkataprasad Bhat S., Harinipriya S., "L-Alanine capping of ZnO nanorods: increased carrier concentration in ZnO/CuI heterojunction diode", RSC Adv.(2018) 8, 5350-5361 [DOI:10.1039/C7RA12385J]
  32. [16] Indubala E., Dhanasekar M., Sudha V., Padma Malar E.J., Divya P., Jositta Sherine, Revathy Rajagopal, Venkataprasad Bhat S., Harinipriya S., "L-Alanine capping of ZnO nanorods: increased carrier concentration in ZnO/CuI heterojunction diode", RSC Adv.(2018) 8, 5350-5361 [DOI:10.1039/C7RA12385J]
  33. [17] Talwatkar S.S., Tamgadge Y.S., Sunatkari A.L., Gambhire A.B., Muley G.G., "Amino acids (L-arginine and L-alanine) passivated CdS nanoparticles: Synthesis of spherical hierarchical structure and nonlinear optical properties", Solid State Sciences; 38 (2014) 42e48 [DOI:10.1016/j.solidstatesciences.2014.09.014]
  34. [17] Talwatkar S.S., Tamgadge Y.S., Sunatkari A.L., Gambhire A.B., Muley G.G., "Amino acids (L-arginine and L-alanine) passivated CdS nanoparticles: Synthesis of spherical hierarchical structure and nonlinear optical properties", Solid State Sciences; 38 (2014) 42e48 [DOI:10.1016/j.solidstatesciences.2014.09.014]
  35. [18] Bindu P., Thomas S., "Estimation of lattice straine in ZnOnanoparticles: X-Ray peak profile analysis", J Theor Appl Phys; (2014) 8:123-134 [DOI:10.1007/s40094-014-0141-9]
  36. [18] Bindu P., Thomas S., "Estimation of lattice straine in ZnOnanoparticles: X-Ray peak profile analysis", J Theor Appl Phys; (2014) 8:123-134 [DOI:10.1007/s40094-014-0141-9]
  37. [19] Gharibshahian E., Jafar Tafershi M., Fazli M., "Effects of solution concentration and capping agents on the properties of potassium titanyl phosphate noparticles synthesized using a co-precipitation method", Journal of Physics and Chemistry of Solids; 116 (2018) 241-249 [DOI:10.1016/j.jpcs.2018.01.015]
  38. [19] Gharibshahian E., Jafar Tafershi M., Fazli M., "Effects of solution concentration and capping agents on the properties of potassium titanyl phosphate noparticles synthesized using a co-precipitation method", Journal of Physics and Chemistry of Solids; 116 (2018) 241-249 [DOI:10.1016/j.jpcs.2018.01.015]
  39. [20] Ganesa Moorthy, Ph.D.Thesis; Anna University;1998
  40. [20] Ganesa Moorthy, Ph.D.Thesis; Anna University;1998
  41. [21] Anitha P., Murganantham N., "Growth and characterization of L-alanine crystals using FT-IR, UV-Visible spectra", Journal of Service Research ;3(2014) 51-56
  42. [21] Anitha P., Murganantham N., "Growth and characterization of L-alanine crystals using FT-IR, UV-Visible spectra", Journal of Service Research ;3(2014) 51-56
  43. [22] Azhang S. A.C., Ganesan S., "Effect of zinc acetate addition on crystal growth, structural, optical, thermal properties of glycine single crystal, Arabian Journal of Chemistry; 10 (2017) S2615,10 pages [DOI:10.1016/j.arabjc.2013.09.041]
  44. [22] Azhang S. A.C., Ganesan S., "Effect of zinc acetate addition on crystal growth, structural, optical, thermal properties of glycine single crystal, Arabian Journal of Chemistry; 10 (2017) S2615,10 pages [DOI:10.1016/j.arabjc.2013.09.041]
  45. [23] Sigaev V.N., Pernice P., Depero L.E, Aronne A., Bontempi E., Akimova O.V., Fanelli E., J. Eur. Ceram. Soc. ; 24(2004)1949-1952 [DOI:10.1016/S0955-2219(03)00423-0]
  46. [23] Sigaev V.N., Pernice P., Depero L.E, Aronne A., Bontempi E., Akimova O.V., Fanelli E., J. Eur. Ceram. Soc. ; 24(2004)1949-1952 [DOI:10.1016/S0955-2219(03)00423-0]
مجله بلورشناسی و کانی شناسی ایران
دوره 29، شماره 1 - شماره پیاپی 81
فروردین 1400
صفحه 249-256

فایل ها

سابقه مقاله

  • تاریخ دریافت: 16 فروردین 1399
  • تاریخ بازنگری: 02 تیر 1399
  • تاریخ پذیرش: 22 مرداد 1399

هم رسانی

ارجاع به این مقاله

آمار