بررسی‌های کانی شناسی و میانبارهای سیال در کانسار طلای زرشوران، شمال تکاب، شمال‌ غرب ایران

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشگاه ارومیه

2 دانشگاه صنعتی ارومیه

3 دانشگاه تبریز

چکیده

کانسار طلای نوع کارلین در زرشوران در فاصله 30 کیلومتری شمال شهرستان تکاب، استان آذربایجان­غربی، شمال­غرب ایران واقع است. واکنش سیال­های کانه­ساز با کربنات­ها و شیل­های میزبان منجر به تشکیل و گسترش پهنه­های دگرسانی دِکربناتی، آرژیلی، آلونیتی، سیلیسی، و سولفیدی در منطقه مورد بررسی شده است. بر اساس بررسی­های میکروسکوپیکی و مزوسکوپیکی صورت گرفته بر نمونه­های مغزه حفاری، کانه­سازی طلا در ارتباط با پیریت­های طلادار و آرسنیک­دار بوده است که طی دو مرحله تشکیل شده­اند. مجموعه کانی­های مربوط به این مراحل شامل پیریت آرسنیک­دار، رالگار، ارپیمنت، سینابر، استیبنیت، و اسفالریت کلوفرم به­ همراه مقادیر کمتری سولفوسالت (تتراهیدریت و گچلیت)­ به صورت همرشدی با ژاسپروئید و کوارتز هستند. بررسی­های ریزدماسنجی بر روی میانبارهای سیال دوفازی غنی از مایع در کوارتزهای خودشکل همرشد با سولفیدهای طلادار نشان داد که سیال­های کانه­ساز دارای میانگین دمای همگن شدگی (Th) حدود 260 درجه سانتی­گراد و شوری­ 2/9 در صد وزنی معادل نمک طعام هستند. روند تغییرات شوری و Th میانبارهای سیال را می­توان با تلفیقی از آمیختگی و رقیق شدن سیال­های کانه­ساز با آب­های زیرزمینی با خاستگاه جوی توضیح داد. این فرآیندها احتمالاً علت اصلی ناپایداری کمپلکس­های طلادار و از اینرو، نهشت طلا در رگه/رگچه­ها هستند. همچنین، براساس فشارهای به دست آمده از یافته­های ریزدماسنجی، عمق­های برآورد شده برای تشکیل کانسنگ در گستره 160 تا 300 متر و فشار 40 تا 75 بار هستند که با بعضی ذخایر طلای نوع کارلین همخوانی دارد. بطورکلی، یافته­های زمین­شناسی، کانی­شناسی، بافتی و ریزدماسنجی شواهد کافی را برای قرارگیری کانه­زایی طلای زرشوران در زمره کانسارهای طلای نوع کارلین فراهم می­نمایند.    

کلیدواژه‌ها


عنوان مقاله [English]

Mineralogy and fluid inclusion investigations in the Zarshuran gold deposit, north of Takab, NW Iran

نویسندگان [English]

  • Tohid Yousefi 1
  • Ali Abedini 1
  • Farhang Aliyari 2
  • AliAsghar Calagari 3
1 Urmia University
2 Urmia University of Technology
3 University of Tabriz
چکیده [English]

The Zarshuran Carlin-type gold deposit is located about 30 km north of Takab, West-Azarbaidjan Province, NW Iran. Interaction between the ore-forming fluids and the host carbonates and shales resulted in development of the decarbonatization, argillic, alunite, silicic, and sulfide alteration zones in the study area. Based on mesoscopic and microscopic studies on drill core samples, gold mineralization is mainly associated with Au-bearing pyrite and arsenic-containing pyrite generated during two stages. The mineral assemblages associated with these stages are As-bearing pyrite, realgar, orpiment, cinnabar, stibnite, and colloform sphalerite together with lesser amounts of sulfosalts (tetrahedrite and getchellite) intergrown with jasperoid and quartz. The microthermometric studies on liquid-rich 2-phase fluid inclusions in euhedral quartz crystals intergrown with the Au-bearing sulfides showed that the ore-forming fluids had an average  homogenization temperature (Th) and salinity of about  260°C and 9.2 wt% NaCl equivalent, respectively. The variation trends in salinity and Th of fluid inclusions could be explained by a combination of mixing and dilution of ore-bearing fluids with subsurface waters of meteoric origin. These processes were likely the principal cause for instability of Au-bearing complexes and hence gold deposition in the veins/veinlets. In addition, on the basis of the obtained pressures from microthermometric data the estimated depths for ore formation were within the range of 160 to 300 meters correlated with 40 to 75 bars, which is in agreement with some known Carlin-type gold deposits. In general, the geological, mineralogical, textural, and microthermometric data provided sufficient evidence to categorize the gold mineralization at Zarshuran as ­­­­­­­Carlin-type

کلیدواژه‌ها [English]

  • Carlin
  • gold mineralization
  • fluid inclusions
  • Carlin-type
  • sulfosalts
  • Zarshuran
  1. [1] Ghasemi A., Talbot C. J., "A new tectonic scenario for the Sanandaj-Sirjan Zone (Iran)", Journal of Asian Earth Sciences 26 (2006) 683-693. [DOI:10.1016/j.jseaes.2005.01.003]
  2. [1] Ghasemi A., Talbot C. J., "A new tectonic scenario for the Sanandaj-Sirjan Zone (Iran)", Journal of Asian Earth Sciences 26 (2006) 683-693. [DOI:10.1016/j.jseaes.2005.01.003]
  3. [2] Daliran F., "The carbonate rock-hosted epithermal gold deposit of Agdarreh, Takab geothermal field, NW Iran-hydrothermal alteration and mineralisation", Mineralium Deposita 43 (2008) 383-404. [DOI:10.1007/s00126-007-0167-x]
  4. [2] Daliran F., "The carbonate rock-hosted epithermal gold deposit of Agdarreh, Takab geothermal field, NW Iran-hydrothermal alteration and mineralisation", Mineralium Deposita 43 (2008) 383-404. [DOI:10.1007/s00126-007-0167-x]
  5. [3] Mehrabi B., Yardley B. W. D., Cann J.R., "Sediment-hosted disseminated gold mineralisation at Zarshuran, NW Iran", Mineralium Deposita 34 (1999) 673-696. [DOI:10.1007/s001260050227]
  6. [3] Mehrabi B., Yardley B. W. D., Cann J.R., "Sediment-hosted disseminated gold mineralisation at Zarshuran, NW Iran", Mineralium Deposita 34 (1999) 673-696. [DOI:10.1007/s001260050227]
  7. [4] Asadi H. H., Voncken J. H. L., Kuhnel R. A., Hale M., "Petrography, Mineralogy and Geochemistry of the Zarshouran Carlin-like gold deposit, northwest Iran", Mineralium deposita 35 (2000) 656-671. [DOI:10.1007/s001260050269]
  8. [4] Asadi H. H., Voncken J. H. L., Kuhnel R. A., Hale M., "Petrography, Mineralogy and Geochemistry of the Zarshouran Carlin-like gold deposit, northwest Iran", Mineralium deposita 35 (2000) 656-671. [DOI:10.1007/s001260050269]
  9. [5] Babakhani A, Ghalamghash J., "The 1:100000 geology map of the Takhte-Soleyman", Geological Survey of Iran (1990).
  10. [5] Babakhani A, Ghalamghash J., "The 1:100000 geology map of the Takhte-Soleyman", Geological Survey of Iran (1990).
  11. [6] Aliyari F., Afzal P., Abdollahi Sharif J., "Determination of geochemical anomalies and gold mineralized stages based on litho-geochemical data for Zarshuran Carlin-like gold deposit (NW Iran) utilizing multi-fractal modeling and stepwise factor analysis", Journal of Mining and Environment 8 (2017) 1-19.
  12. [6] Aliyari F., Afzal P., Abdollahi Sharif J., "Determination of geochemical anomalies and gold mineralized stages based on litho-geochemical data for Zarshuran Carlin-like gold deposit (NW Iran) utilizing multi-fractal modeling and stepwise factor analysis", Journal of Mining and Environment 8 (2017) 1-19.
  13. [7] Whitney D.L., Evans B.W., "Abbreviations for Names of Rock-Forming Minerals", American Mineralogist, 95 (2010) 185-187. [DOI:10.2138/am.2010.3371]
  14. [7] Whitney D.L., Evans B.W., "Abbreviations for Names of Rock-Forming Minerals", American Mineralogist, 95 (2010) 185-187. [DOI:10.2138/am.2010.3371]
  15. [8] Cline J., Hofstra A., Muntean J., Tosdal R., Hickey K., "Carlin-type gold deposits in Nevada: Critical geologic characteristics and viable models", in Hedenquist, J.W., Thompson, J. F. H., Goldfarb, R. J., and Richards, J. P., eds., 100th Anniversary Volume: Society of Economic Geologists, Littleton, CO (2005) 451-484. [DOI:10.5382/AV100.15]
  16. [8] Cline J., Hofstra A., Muntean J., Tosdal R., Hickey K., "Carlin-type gold deposits in Nevada: Critical geologic characteristics and viable models", in Hedenquist, J.W., Thompson, J. F. H., Goldfarb, R. J., and Richards, J. P., eds., 100th Anniversary Volume: Society of Economic Geologists, Littleton, CO (2005) 451-484. [DOI:10.5382/AV100.15]
  17. [9] Lubben J. D., Cline J. S., Barker S. L. L., "Ore Fluid Properties and Sources from Quartz-Associated Gold at the Betze-Post Carlin-Type Gold Deposit, Nevada, United States", Economic Geology 107 (2012) 1351-1385. [DOI:10.2113/econgeo.107.7.1351]
  18. [9] Lubben J. D., Cline J. S., Barker S. L. L., "Ore Fluid Properties and Sources from Quartz-Associated Gold at the Betze-Post Carlin-Type Gold Deposit, Nevada, United States", Economic Geology 107 (2012) 1351-1385. [DOI:10.2113/econgeo.107.7.1351]
  19. [10] Emsbo P., Hofstra A. H., Lauha E. A., Griffin G. L., Hutchinson R. W., John D. A., Theodore T. G. "Origin of high-grade gold ore, source of ore fluid components and genesis of the Meikle and neighboring Carlin-type deposits, northern Carlin Trend, Nevada", Economic Geology 98 (2003) 1069-1105. [DOI:10.2113/gsecongeo.98.6.1069]
  20. [10] Emsbo P., Hofstra A. H., Lauha E. A., Griffin G. L., Hutchinson R. W., John D. A., Theodore T. G. "Origin of high-grade gold ore, source of ore fluid components and genesis of the Meikle and neighboring Carlin-type deposits, northern Carlin Trend, Nevada", Economic Geology 98 (2003) 1069-1105. [DOI:10.2113/gsecongeo.98.6.1069]
  21. [11] Shepherd T. J., Rankin A. H., Alderton, D. H., "A practical guide to fluid inclusion studies", Glasgow, Blackie and Son (1985) 239.
  22. [11] Shepherd T. J., Rankin A. H., Alderton, D. H., "A practical guide to fluid inclusion studies", Glasgow, Blackie and Son (1985) 239.
  23. [12] Roedder E.,"Discussion of a reassessment of phase-equilibria involving 2 liquids in the system K2O-Al2O3-FeO-SiO2", Contributions to Mineralogy and Petrology 82 (1984) 284-290. [DOI:10.1007/BF01166622]
  24. [12] Roedder E.,"Discussion of a reassessment of phase-equilibria involving 2 liquids in the system K2O-Al2O3-FeO-SiO2", Contributions to Mineralogy and Petrology 82 (1984) 284-290. [DOI:10.1007/BF01166622]
  25. [13] Bodnar R. J., "Introduction to aqueous-electrolyte fluid inclusions. Fluid Inclusions: Analysis and Interpretation", Mineralogical Association of Canada, Short Course 32 (2003) 81-100.
  26. [13] Bodnar R. J., "Introduction to aqueous-electrolyte fluid inclusions. Fluid Inclusions: Analysis and Interpretation", Mineralogical Association of Canada, Short Course 32 (2003) 81-100.
  27. [14] Hofstra A. H., Cline J. S., "Characteristics and models for Carlin-type gold deposits", Reviews in Economic Geology 13 (2000) 163-220.
  28. [14] Hofstra A. H., Cline J. S., "Characteristics and models for Carlin-type gold deposits", Reviews in Economic Geology 13 (2000) 163-220.
  29. [15] Lubben J. D., "Silicification Across the Betze-Post Carlin-Type Au Deposit: Clues to Ore Fluid Properties and Sources, Northern Carlin Trend, Nevada [MS Unpublished MS Thesis", University of Nevada, Las Vegas, (2004) 155.
  30. [15] Lubben J. D., "Silicification Across the Betze-Post Carlin-Type Au Deposit: Clues to Ore Fluid Properties and Sources, Northern Carlin Trend, Nevada [MS Unpublished MS Thesis", University of Nevada, Las Vegas, (2004) 155.
  31. [16] Large S.J.E., Bakker E.Y.N., Weis P., Wälle M., Ressel M., Heinrich C.A.,. "Trace elements in fluid inclusions of sediment-hosted gold deposits indicate a magmatic-hydrothermal origin of the Carlin ore trend". Geology. 44(12) (2016) 1015-1018. [DOI:10.1130/G38351.1]
  32. [16] Large S.J.E., Bakker E.Y.N., Weis P., Wälle M., Ressel M., Heinrich C.A.,. "Trace elements in fluid inclusions of sediment-hosted gold deposits indicate a magmatic-hydrothermal origin of the Carlin ore trend". Geology. 44(12) (2016) 1015-1018. [DOI:10.1130/G38351.1]
  33. [17] Jun C., Rui-Dong Y., Li J.D., Lu-L.Z., Jun B.G., Chun K.L., Huai R.W., Ming G.Y., "Mineralogy, geochemistry and fluid inclusions of the Qinglong Sb-(Au) deposit, Youjiang basin (Guizhou, SW China)", Ore Geology Reviews 92 (2018) 1-18. [DOI:10.1016/j.oregeorev.2017.11.009]
  34. [17] Jun C., Rui-Dong Y., Li J.D., Lu-L.Z., Jun B.G., Chun K.L., Huai R.W., Ming G.Y., "Mineralogy, geochemistry and fluid inclusions of the Qinglong Sb-(Au) deposit, Youjiang basin (Guizhou, SW China)", Ore Geology Reviews 92 (2018) 1-18. [DOI:10.1016/j.oregeorev.2017.11.009]
  35. [18] Su W.C., Zhu L.Y., Ge X., Shen N.P., Zhang X.C., Hu R.Z., "Infrared microthermometry of fluid inclusions in stibnite from the Dachang antimony deposit, Guizhou". Acta Petrol Sin. 31 (4) (2015) 918-924 (in Chinese with English abstract).
  36. [18] Su W.C., Zhu L.Y., Ge X., Shen N.P., Zhang X.C., Hu R.Z., "Infrared microthermometry of fluid inclusions in stibnite from the Dachang antimony deposit, Guizhou". Acta Petrol Sin. 31 (4) (2015) 918-924 (in Chinese with English abstract).
  37. [19] Nigel J.F. Blamey, Andrew R. Campbell., Matt T. Heizler, "The Hydrothermal Fluid Evolution of Vein Sets at the Pipeline Gold Mine", Nevada:, Minerals 100 (2017) 1-30. [DOI:10.1016/j.mineng.2016.10.002]
  38. [19] Nigel J.F. Blamey, Andrew R. Campbell., Matt T. Heizler, "The Hydrothermal Fluid Evolution of Vein Sets at the Pipeline Gold Mine", Nevada:, Minerals 100 (2017) 1-30. [DOI:10.1016/j.mineng.2016.10.002]
  39. [20] Hofstra, A. H.,"Geology and genesis of the Carlin-type Au deposits in the Jerritt Canyon district, Nevada", Unpublished PhD (Doctoral dissertation, dissertation, Boulder, University of Colorado, (1994).
  40. [20] Hofstra, A. H.,"Geology and genesis of the Carlin-type Au deposits in the Jerritt Canyon district, Nevada", Unpublished PhD (Doctoral dissertation, dissertation, Boulder, University of Colorado, (1994).
  41. [21] Bodnar R. J.,"A method of calculating fluid inclusion volumes based on vapor bubble diameters and PVTX properties of inclusion fluids", Economic Geology 78 (1983) 535-542. [DOI:10.2113/gsecongeo.78.3.535]
  42. [21] Bodnar R. J.,"A method of calculating fluid inclusion volumes based on vapor bubble diameters and PVTX properties of inclusion fluids", Economic Geology 78 (1983) 535-542. [DOI:10.2113/gsecongeo.78.3.535]
  43. [22] Wilkinson J. J., "Fluid inclusions in hydrothermal ore deposits", Lithos 55 (2001) 229-272. [DOI:10.1016/S0024-4937(00)00047-5]
  44. [22] Wilkinson J. J., "Fluid inclusions in hydrothermal ore deposits", Lithos 55 (2001) 229-272. [DOI:10.1016/S0024-4937(00)00047-5]
  45. [23] Haas J. L., "Physical properties of the co-existing phases and thermometrical properties of H2O component in boiling NaCl solutions: Preliminary steam tables for NaCl solutions", United States Geological Survey Bulletin, (1976) 1421-A.
  46. [23] Haas J. L., "Physical properties of the co-existing phases and thermometrical properties of H2O component in boiling NaCl solutions: Preliminary steam tables for NaCl solutions", United States Geological Survey Bulletin, (1976) 1421-A.
  47. [24] Urusova M. A., "Volume properties of aqueous solutions of sodium chloride at elevated temperatures and pressures", Russian Journal o Inorganic Chemistry 20 (1975) 1717-1721.
  48. [24] Urusova M. A., "Volume properties of aqueous solutions of sodium chloride at elevated temperatures and pressures", Russian Journal o Inorganic Chemistry 20 (1975) 1717-1721.
  49. [25] Rossetti P., Colombo F., "Adularia-sericite gold deposits of Marmato_Caldas, Colombia.: field and petrographic data", In: McCaffrey K.J.W., Lonergan L., Wilkinson J.J.-Eds.., Fractures, "Fluid Flow and Mineralization. Geological Society of London", Special Publications 155 (1999) 167-182. [DOI:10.1144/GSL.SP.1999.155.01.13]
  50. [25] Rossetti P., Colombo F., "Adularia-sericite gold deposits of Marmato_Caldas, Colombia.: field and petrographic data", In: McCaffrey K.J.W., Lonergan L., Wilkinson J.J.-Eds.., Fractures, "Fluid Flow and Mineralization. Geological Society of London", Special Publications 155 (1999) 167-182. [DOI:10.1144/GSL.SP.1999.155.01.13]
  51. [26] Hofstra A. H., Leventhal J. S., Northrop H. R., Landis G. P., Rye R. O., Birak D. J., Dahl A. R., "Genesis of sediment-hosted disseminated-gold deposits by fluid mixing and sulfidization; chemical-reaction-path modeling of ore depositional processes documented in the Jerritt Canyon District, Nevada", Geology19(1991)36-40.

    https://doi.org/10.1130/0091-7613(1991)0192.3.CO;2 [DOI:10.1130/0091-7613(1991)0192.3.CO;2]
  52. [26] Hofstra A. H., Leventhal J. S., Northrop H. R., Landis G. P., Rye R. O., Birak D. J., Dahl A. R., "Genesis of sediment-hosted disseminated-gold deposits by fluid mixing and sulfidization; chemical-reaction-path modeling of ore depositional processes documented in the Jerritt Canyon District, Nevada", Geology19(1991)36-40.

    https://doi.org/10.1130/0091-7613(1991)0192.3.CO;2 [DOI:10.1130/0091-7613(1991)0192.3.CO;2]