Preparation and investigation of magnetic properties of Manganese Cadmium ferrite nanoparticles by Sol-gel method

Document Type : Original Article

Authors

Abstract

In the present investigation, manganese ferrite nanoparticles substituted by cadmium with Mn1-xCdxFe2O4 composition and substituted amount x=(0, 0.1, 0.3, 0.5) were prepared by Sol-gel method. Pattern analysis of X-ray diffraction (XRD) confirmed ferrite single phase structure in all samples. The average crystal size was estimated from 17 to 22 nm. The chemical bonds and ferrite formation phase of samples were analyzed by Far-FTIR and FT-IR analyses. The prepared magnetic properties of nanoparticles were analyzed by Vibrating Sample Magnetometer (VSM) which shows that saturation magnetization changes by substitution of Cd2+  in manganese ferrite. These changes are formed by cation distribution among tetrahedral and octahedral sites and superexchange interaction decrease.

Keywords

References

  1. [1] Ahmed M.A., Dkasha N., EL-Dek I.S.I., "Perparation and characterization of nano magnetic Mn ferrite via different methods", Nanotechnology 19(2008)065603(6pp). [DOI:10.1088/0957-4484/19/6/065603]
  2. [1] Ahmed M.A., Dkasha N., EL-Dek I.S.I., "Perparation and characterization of nano magnetic Mn ferrite via different methods", Nanotechnology 19(2008)065603(6pp). [DOI:10.1088/0957-4484/19/6/065603]
  3. [2] Abdallah H.M.I., Moyo T., Somi M.J.Z., "Mossbauer and electrical studies of Co-Mn compound perpared via glycothermal route", J.Supercond Nov Magn(2010).
  4. [2] Abdallah H.M.I., Moyo T., Somi M.J.Z., "Mossbauer and electrical studies of Co-Mn compound perpared via glycothermal route", J.Supercond Nov Magn(2010).
  5. [3] Shobana M., Sankar, "Characterization of Sol gel perpared nano ferrites", Fundametal Magnetism and Magnetic Materials 321(2009) 599- 601. [DOI:10.1016/j.jmmm.2008.09.040]
  6. [3] Shobana M., Sankar, "Characterization of Sol gel perpared nano ferrites", Fundametal Magnetism and Magnetic Materials 321(2009) 599- 601. [DOI:10.1016/j.jmmm.2008.09.040]
  7. [4] Saotome H., Tachibana K., "Frequency characteristies of the complex permeability of ferrites", Journal of Magnetic Society of Japan 22(1998) 289-291. [DOI:10.3379/jmsjmag.22.S1_289]
  8. [4] Saotome H., Tachibana K., "Frequency characteristies of the complex permeability of ferrites", Journal of Magnetic Society of Japan 22(1998) 289-291. [DOI:10.3379/jmsjmag.22.S1_289]
  9. [5] Rozman M., Drofenik M., "Sintering of nanosized Mn-Zn ferrite powders", Journal of the American Ceramic Society 81(1998) 1757- 1764. [DOI:10.1111/j.1151-2916.1998.tb02545.x]
  10. [5] Rozman M., Drofenik M., "Sintering of nanosized Mn-Zn ferrite powders", Journal of the American Ceramic Society 81(1998) 1757- 1764. [DOI:10.1111/j.1151-2916.1998.tb02545.x]
  11. [6] Nasr B., Amighian J., Mozaffar M., "The effect of temperature and atmosphere on spinel phase formation of nano-manganese ferrite", IJPR 6 (1) (2006) 49-52 .
  12. [6] Nasr B., Amighian J., Mozaffar M., "The effect of temperature and atmosphere on spinel phase formation of nano-manganese ferrite", IJPR 6 (1) (2006) 49-52 .
  13. [7] Chen S.H., Chang S.C., Lin I.N., "The influence of grain boundary internal stress on permeability: temperature curve for Mn-Zn ferrites", Journal of Magn. Magn. Mater 209(2000)193-196. [DOI:10.1016/S0304-8853(99)00685-X]
  14. [7] Chen S.H., Chang S.C., Lin I.N., "The influence of grain boundary internal stress on permeability: temperature curve for Mn-Zn ferrites", Journal of Magn. Magn. Mater 209(2000)193-196. [DOI:10.1016/S0304-8853(99)00685-X]
  15. [8] Pradhan S.K., Bid S., Gateshki S., Petkav S., "Microstructure characterization and cation distribution of nanocrystalline magnesium ferrite prepared by ball milling", Materials Chimistry and Physics 93(2005)225-230. [DOI:10.1016/j.matchemphys.2005.03.017]
  16. [8] Pradhan S.K., Bid S., Gateshki S., Petkav S., "Microstructure characterization and cation distribution of nanocrystalline magnesium ferrite prepared by ball milling", Materials Chimistry and Physics 93(2005)225-230. [DOI:10.1016/j.matchemphys.2005.03.017]
  17. [9] Abbas Y.M., Mansour S.A., Ibrahim H.M., Shehab E.Ali., "Microstructure characterization and cation distribution of nanocrystalline cobalt ferrite", Journal of Magn and Magn Mater 323 (2011)2748-2756. [DOI:10.1016/j.jmmm.2011.05.038]
  18. [9] Abbas Y.M., Mansour S.A., Ibrahim H.M., Shehab E.Ali., "Microstructure characterization and cation distribution of nanocrystalline cobalt ferrite", Journal of Magn and Magn Mater 323 (2011)2748-2756. [DOI:10.1016/j.jmmm.2011.05.038]
  19. [10] Bid S., Pradhan S.K., "Characterization of crystalline structure of ball-milled nano-Ni-Zn-ferrite by Rietveld method", Materials Chimistry and Physics84(2004)291-301. [DOI:10.1016/j.matchemphys.2003.08.012]
  20. [10] Bid S., Pradhan S.K., "Characterization of crystalline structure of ball-milled nano-Ni-Zn-ferrite by Rietveld method", Materials Chimistry and Physics84(2004)291-301. [DOI:10.1016/j.matchemphys.2003.08.012]
  21. [11] Mazen S.A., Sabrah B.A., "Thermal effect on formation and conduction mechanism of MnFe2O4, Acta105(1986) 1-8. [DOI:10.1016/0040-6031(86)85217-0]
  22. [11] Mazen S.A., Sabrah B.A., "Thermal effect on formation and conduction mechanism of MnFe2O4, Acta105(1986) 1-8. [DOI:10.1016/0040-6031(86)85217-0]
  23. [12] Ismail S.M., Labib Sh., Attallah S.S., "Perparation Characterization of Nano-Cadmium Ferrite", Journal of Ceramics 6(2013)8. [DOI:10.1155/2013/526434]
  24. [12] Ismail S.M., Labib Sh., Attallah S.S., "Perparation Characterization of Nano-Cadmium Ferrite", Journal of Ceramics 6(2013)8. [DOI:10.1155/2013/526434]
  25. [13] Nayak P.K., "Synthesis and characterization of Cadmium ferrite", Materials Chemistry and Physics 112(2008)24-26. [DOI:10.1016/j.matchemphys.2008.05.018]
  26. [13] Nayak P.K., "Synthesis and characterization of Cadmium ferrite", Materials Chemistry and Physics 112(2008)24-26. [DOI:10.1016/j.matchemphys.2008.05.018]
  27. [14] Ramesh B., Ramesh S., Vijaya Kumer R., Lakshmipathi Rao.M., "AC impedance studies on Li F5-X MnxO8 ferrites", Journal of Alloys and Compounds 513(2012) 289-293. [DOI:10.1016/j.jallcom.2011.10.038]
  28. [14] Ramesh B., Ramesh S., Vijaya Kumer R., Lakshmipathi Rao.M., "AC impedance studies on Li F5-X MnxO8 ferrites", Journal of Alloys and Compounds 513(2012) 289-293. [DOI:10.1016/j.jallcom.2011.10.038]
  29. [15] Hashim M., Alimuddin K., Kumar S., Ali S., Koo B.H., Chang H., Kumar R., "Structural, magnetic and electrical properties of Al3+ substituted Ni-Zn ferrite nanoparticles", Journal of Alloys and Compounds511(2012)107-114. [DOI:10.1016/j.jallcom.2011.08.096]
  30. [15] Hashim M., Alimuddin K., Kumar S., Ali S., Koo B.H., Chang H., Kumar R., "Structural, magnetic and electrical properties of Al3+ substituted Ni-Zn ferrite nanoparticles", Journal of Alloys and Compounds511(2012)107-114. [DOI:10.1016/j.jallcom.2011.08.096]
  31. [16] Khan M.A., Islam M.U., Ishaque M., Rahman I.Z., "Magnetic and dielectric behavior of terbium substituted Mg1-xTbxFe2O4 ferrites", Journal of Alloys and Compounds512(2012)156. [DOI:10.1016/j.jallcom.2011.12.159]
  32. [16] Khan M.A., Islam M.U., Ishaque M., Rahman I.Z., "Magnetic and dielectric behavior of terbium substituted Mg1-xTbxFe2O4 ferrites", Journal of Alloys and Compounds512(2012)156. [DOI:10.1016/j.jallcom.2011.12.159]
  33. [17] Rajesh Iyer., Rucha Desai., Upadhyay R.V., "Low tempreature synthesis of nanosized Mn1-xCdxFe2O4 ferrite", Indian Journal of Pure & Applied Physics Vol47(2009)180-185. [DOI:10.1007/s12034-009-0021-0]
  34. [17] Rajesh Iyer., Rucha Desai., Upadhyay R.V., "Low tempreature synthesis of nanosized Mn1-xCdxFe2O4 ferrite", Indian Journal of Pure & Applied Physics Vol47(2009)180-185. [DOI:10.1007/s12034-009-0021-0]
  35. [18] Mazen A., ABD-EL-RAIEM.A.E., "The structure and electrical conductivity of Mn-Cd ferrite", Journal of Materials Science 22(1987)4177-4180. [DOI:10.1007/BF01133376]
  36. [18] Mazen A., ABD-EL-RAIEM.A.E., "The structure and electrical conductivity of Mn-Cd ferrite", Journal of Materials Science 22(1987)4177-4180. [DOI:10.1007/BF01133376]
  37. [19] Nasser Y., Mostafa Zaki Z.I., Heiba Z.K., "Structural and magnetic propertize of Cadmium substituted mangenese ferrite prepared by Hedrothermal route", J. Magn. Magn. Mater 329(2013) 71-76. [DOI:10.1016/j.jmmm.2012.09.004]
  38. [19] Nasser Y., Mostafa Zaki Z.I., Heiba Z.K., "Structural and magnetic propertize of Cadmium substituted mangenese ferrite prepared by Hedrothermal route", J. Magn. Magn. Mater 329(2013) 71-76. [DOI:10.1016/j.jmmm.2012.09.004]
  39. [20] XiG. Yang.L., Lu.M., "Study on preparation of nanocrystalline ferrites using spent Alkaline Zn- Mn battries", Materials Letters 60(2006) 3582-3585. [DOI:10.1016/j.matlet.2006.03.064]
  40. [20] XiG. Yang.L., Lu.M., "Study on preparation of nanocrystalline ferrites using spent Alkaline Zn- Mn battries", Materials Letters 60(2006) 3582-3585. [DOI:10.1016/j.matlet.2006.03.064]
  41. [21] Akbarii F., Niyaifar M., Hanatehzadeh M., "Study of the structural and magnetic properties of Ni0.65Zn0.35CuxFe2-xO4 ferrite nanoparticle", Iranian Journal of Crystallography and Mineralogy 23(2)(2015) 277-284.
  42. [21] Akbarii F., Niyaifar M., Hanatehzadeh M., "Study of the structural and magnetic properties of Ni0.65Zn0.35CuxFe2-xO4 ferrite nanoparticle", Iranian Journal of Crystallography and Mineralogy 23(2)(2015) 277-284.
  43. [22] Deraz N.M., Alarifi A., "Controlled synthesis, physicochemical and magnetic properties of nano- crystalline Mn ferrite system", Int.J.Electrochem.Sci 7 (2012) 5534-5543.
  44. [22] Deraz N.M., Alarifi A., "Controlled synthesis, physicochemical and magnetic properties of nano- crystalline Mn ferrite system", Int.J.Electrochem.Sci 7 (2012) 5534-5543.
  45. [23] Hasting J.M., Corliss L.M., "An Antiferromagnetic Transition in Zinc Ferrite", Phys.Rev 102(1956) 1460. [DOI:10.1103/PhysRev.102.1460]
  46. [23] Hasting J.M., Corliss L.M., "An Antiferromagnetic Transition in Zinc Ferrite", Phys.Rev 102(1956) 1460. [DOI:10.1103/PhysRev.102.1460]
  47. [24] Chhantbar M.C., Trived U.N., Tanna P.V., Shah H.J., Vara R.P., Joshi H.H., Modi K.B., "Infrared spectra studies of Zn- substituted CuFeCrO4 spinel ferrite system", Indian.J.Phys 78A(2004) 321-326.
  48. [24] Chhantbar M.C., Trived U.N., Tanna P.V., Shah H.J., Vara R.P., Joshi H.H., Modi K.B., "Infrared spectra studies of Zn- substituted CuFeCrO4 spinel ferrite system", Indian.J.Phys 78A(2004) 321-326.
  49. [25] Raghavender A.T., Biliskiv N., Skoko Z., "XRD and IR analysis of nano crystalline Ni-Zn ferrite synthesized by Sol-gel method", Mater.Lett 65(2011) 677-680. [DOI:10.1016/j.matlet.2010.11.071]
  50. [25] Raghavender A.T., Biliskiv N., Skoko Z., "XRD and IR analysis of nano crystalline Ni-Zn ferrite synthesized by Sol-gel method", Mater.Lett 65(2011) 677-680. [DOI:10.1016/j.matlet.2010.11.071]
  51. [26] Zaki H.M., Dawoud H.A., "Far-Infrared spectra for Copper - Zink mixed ferrites", Physica.B 405(2010) 4476- 4479. [DOI:10.1016/j.physb.2010.08.018]
  52. [26] Zaki H.M., Dawoud H.A., "Far-Infrared spectra for Copper - Zink mixed ferrites", Physica.B 405(2010) 4476- 4479. [DOI:10.1016/j.physb.2010.08.018]
  53. [27] Levine B.F., "d-Electron effects on bound suscepibilities and ionicities", Phys.Rev.B 7(1973) 2591- 2599. [DOI:10.1103/PhysRevB.7.2591]
  54. [27] Levine B.F., "d-Electron effects on bound suscepibilities and ionicities", Phys.Rev.B 7(1973) 2591- 2599. [DOI:10.1103/PhysRevB.7.2591]
  55. [28] Bhandarea M.R., Jamadarab H.V., Pathanb A.T., Chouguleb B.K., Shaikhc A.M., "Dielectric properties of Cu substituted Ni0.5-xZn0.3Mg0.2Fe2O4 ferrites", Journal of Alloys and Compounds 509( 2011)113-118. [DOI:10.1016/j.jallcom.2010.11.173]
  56. [28] Bhandarea M.R., Jamadarab H.V., Pathanb A.T., Chouguleb B.K., Shaikhc A.M., "Dielectric properties of Cu substituted Ni0.5-xZn0.3Mg0.2Fe2O4 ferrites", Journal of Alloys and Compounds 509( 2011)113-118. [DOI:10.1016/j.jallcom.2010.11.173]
  57. [29] Nath B.K., Chakrabarti P.K., Das S., Kumer U., Mukhopadhyay and Das.D., "Mossbauer studies on nanoparticles of Zink substituted magnetism ferrite", J.Surface.Sci.Technol 21(2005) 169-182.
  58. [29] Nath B.K., Chakrabarti P.K., Das S., Kumer U., Mukhopadhyay and Das.D., "Mossbauer studies on nanoparticles of Zink substituted magnetism ferrite", J.Surface.Sci.Technol 21(2005) 169-182.
  59. [30] Mohamedda K.A., Rawas A.D.AL., Gismelseed A.M.B., Sellai B.A., Widatallah H.M., Yousif B.A., Elzain B.M.E., Shonqwe M., "Infrared and structural studies of Mg-Zn ferrite", Physica .B 407(2012) 795- 804. [DOI:10.1016/j.physb.2011.12.097]
  60. [30] Mohamedda K.A., Rawas A.D.AL., Gismelseed A.M.B., Sellai B.A., Widatallah H.M., Yousif B.A., Elzain B.M.E., Shonqwe M., "Infrared and structural studies of Mg-Zn ferrite", Physica .B 407(2012) 795- 804. [DOI:10.1016/j.physb.2011.12.097]
  61. [31] Niyaifar M., Nazarii S., Hasanpour A., "Effect of Zn substitution on varation microscopic structural and magnetic properties of MgZn ferrite", Iranian Journal of Crystallography and Mineralogy 23(3)(2015) 507-516.
  62. [31] Niyaifar M., Nazarii S., Hasanpour A., "Effect of Zn substitution on varation microscopic structural and magnetic properties of MgZn ferrite", Iranian Journal of Crystallography and Mineralogy 23(3)(2015) 507-516.
  63. [32] Lan N.T., Hien T.D., Duong N.P., Truong D.V., "Magnetic properties of Mn1-xZnxFe2O4 ferrite nanoparticles prepared by using Co-Precipitation", Journal of Korean Physical Society 52(5)(2008) 1522-1525. [DOI:10.3938/jkps.52.1522]
  64. [32] Lan N.T., Hien T.D., Duong N.P., Truong D.V., "Magnetic properties of Mn1-xZnxFe2O4 ferrite nanoparticles prepared by using Co-Precipitation", Journal of Korean Physical Society 52(5)(2008) 1522-1525. [DOI:10.3938/jkps.52.1522]
  65. [33] Muroi K., Amighian J., Street R., Mccormiks P., "Magnetic properties of ultrafine MnFe2O4 powders prepared by mechanochemical processing", Phys.Rev.B63(2001)184-414. [DOI:10.1103/PhysRevB.63.184414]
  66. [33] Muroi K., Amighian J., Street R., Mccormiks P., "Magnetic properties of ultrafine MnFe2O4 powders prepared by mechanochemical processing", Phys.Rev.B63(2001)184-414. [DOI:10.1103/PhysRevB.63.184414]

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  • Receive Date: 05 May 2018
  • Revise Date: 29 September 2018
  • Accept Date: 03 November 2018

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