ساخت نانوذرات فریت منگنز کادمیم به روش سل-ژل و بررسی ویژگی‌های مغناطیسی آنها

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه آزاد اسلامی

چکیده

در این پژوهش، نانوذرات فریت منگنز جانشانی شده با کادمیم با فرمول شیمیایی Mn1-xCdxFe2O4 و مقادیر جانشانی (5/0, 3/0, 1/0, 0)x=  به روش سل­ژل تهیه شدند. تحلیل الگوهای پراش پرتو ایکس (XRD) ساختار تک فاز فریت را در همه­ی  نمونه­ها تأیید کرد. میانگین اندازه بلورک­ها از ۱۷ تا ۲۲ نانومتر برآورد شد. با استفاده از طیف­ سنجی­های تبدیل فوریه فروسرخ (FT-IR) وفروسرخ دور  (Far-FTIR)پیوندهای شیمیایی و فاز تشکیل فریت نمونه­ها بررسی گردید. ویژگی­های مغناطیسی نانوذرات تهیه شده توسط مغناطش سنج نمونه ارتعاشی (VSM) بررسی شد و نتایج نشان داد که در اثر جانشانی یون­های  در فریت منگنز، مغناطش اشباع به صورت غیرخطی تغییر می­کند این تغییرات به توزیع کاتیون­ها در جایگاه­های چاروجهی و هشت­وجهی و هم­چنین کاهش بر­هم­کنش ابر­تبادلی نسبت داده می­شود.     

کلیدواژه‌ها

عنوان مقاله [English]

Preparation and investigation of magnetic properties of Manganese Cadmium ferrite nanoparticles by Sol-gel method

نویسندگان [English]

  • Mohammad Niyaifar
  • Mahboubeh Heidari
چکیده [English]

In the present investigation, manganese ferrite nanoparticles substituted by cadmium with Mn1-xCdxFe2O4 composition and substituted amount x=(0, 0.1, 0.3, 0.5) were prepared by Sol-gel method. Pattern analysis of X-ray diffraction (XRD) confirmed ferrite single phase structure in all samples. The average crystal size was estimated from 17 to 22 nm. The chemical bonds and ferrite formation phase of samples were analyzed by Far-FTIR and FT-IR analyses. The prepared magnetic properties of nanoparticles were analyzed by Vibrating Sample Magnetometer (VSM) which shows that saturation magnetization changes by substitution of Cd2+  in manganese ferrite. These changes are formed by cation distribution among tetrahedral and octahedral sites and superexchange interaction decrease.

کلیدواژه‌ها [English]

  • Nanoparticles
  • Mn-Cd ferrite
  • magnetic properties
  • spinel structure

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  • تاریخ دریافت: 15 اردیبهشت 1397
  • تاریخ بازنگری: 07 مهر 1397
  • تاریخ پذیرش: 12 آبان 1397

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