تاثیر دما و مقدار نیترات بیسموت بر ویژگی‌های ساختاری، مغناطیسی و فوتوکاتالیزوری فریت بیسموت

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه دامغان

چکیده

در این پژوهش، تأثیر دما و مقدار نیترات بیسموت بر ویژگی­های ساختاری، مغناطیسی و فوتوکاتالیزوری نانوذرات چندفروئی فریت بیسموت تهیه شده به روش سیترات نیترات بررسی شده­اند. ویژگی­های ساختاری و مغناطیسی به­وسیله پراش پرتو ایکس (XRD)، طیف­سنجی تبدیل فوریه فروسرخ (FTIR) و مغناطیس­سنج نمونه ارتعاشی در دمای اتاق بررسی شد. تحلیل الگوهای XRD و داده­های FTIR نشان داد که فاز خالص فریت بیسموت فقط با ثابت ماندن مقدار مول نیترات بیسموت در محلول و در دمای ºC650 به دست می­آید. براساس نتایج مغناطیسی و فوتوکاتالیزوری نیز روشن شد که حضور فازهای ناخالصی سبب بوجود آمدن رفتار فرومغناطیسی قوی در نمونه­ها می­شود، اما تاثیر منفی بر ویژگی­های فوتوکاتالیزوری فریت بیسموت دارد.      

کلیدواژه‌ها

عنوان مقاله [English]

Effect of temperature and concentration of bismuth nitrate mole on structural, magnetic and photocatalytic properties of bismuth ferrite

نویسندگان [English]

  • Laila Esmaili
  • Ahmad Gholizadeh
Damghan University
چکیده [English]

In this research, the effect of temperature and concentration of bismuth nitrate mole on structural, magnetic and photocatalytic properties of the bismuth ferrite nanoparticles prepared by nitrate-citrate method have been investigated. The structural and magnetic properties were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and vibrating-sample magnetometer at room temperature. An important role in the synthesis of pure bismuth ferrite is played by temperature and excess bismuth oxide. Analysis of XRD patterns and FTIR data indicate that to obtain the pure bismuth ferrite, a stoichiometric amount of bismuth nitrate mole in solution and sintering at temperature 650 °C is needed. The magnetic and photocatalytic results have showed that the presence of the impurity phases led to strong ferromagnetic behavior in samples, but has a negative effect on the photocatalytic properties of bismuth ferrite.

کلیدواژه‌ها [English]

  • Nanoparticles
  • bismuth ferrite
  • citrate method
  • structural
  • magnetic and photocatalytic properties

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سابقه مقاله

  • تاریخ دریافت: 30 بهمن 1396
  • تاریخ بازنگری: 17 فروردین 1397
  • تاریخ پذیرش: 22 اردیبهشت 1397

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