سنتز، شناسایی و تعیین ساختار بلوری پلیمر کوئوردیناسیونی جدید از کادمیم (II) بر پایه‌ی لیگاندهای پیریدین هیدرازید

نوع مقاله : مقاله پژوهشی

نویسنده

دانشگاه شهید بهشتی

چکیده

دو ترکیب پلیمری جدید از کادمیم استات با استفاده از دو ایزومر از لیگاندهای پیریدین هیدرازید تهیه و ساختار آن‌ها به روش پراش پرتو ایکس تک بلور شناسایی شد. بررسی‌های ساختاری نشان داد که هر دو ترکیب در سیستم بلوری تک­میل و گروه فضایی P < /span>21/c متبلور شده‌اند. پلیمر کوئوردیناسیونی [Cd(OAc)2(L1H)]n که در آن L1H، پارا پیریدین هیدرازید است، دارای صفحه‌های دوبعدی و شبکه‌های مستطیلی و پلیمر [Cd2(OAc)3(L2H)L2(EtOH)]n که در آن L2H، متاپیریدین هیدرازید است، دارای صفحه‌های دوبعدی و طرح جناقی هستند.    

کلیدواژه‌ها

عنوان مقاله [English]

Synthesis, characterization and crystal structure determination of new coordination polymers of cadmium (II) based on pyridine hydrazide ligands

نویسنده [English]

  • Behrouz Notash
Shahid Beheshti University
چکیده [English]

Two new polymeric compounds of cadmium acetate using two isomers of pyridine hydrazide ligands have been synthesized and characterized by X-ray diffraction analysis. Structural analysis shows that both compounds were crystallized in monoclinic crystal system with P21/c space group. Coordination polymer [Cd(OAc)2(L1H)]n (1) which L1H is para pyridine hydrazide, has two dimensional sheets with rectangular net and coordination polymer [Cd2(OAc)3(L2H)L2(EtOH)]n (2) which L2H is meta pyridine hydrazide, has got herringbone structure in 2D dimension.

کلیدواژه‌ها [English]

  • Coordination polymer
  • crystal structure
  • monoclinic
  • hydrogen bonding
  • cadmium

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  • تاریخ دریافت: 25 بهمن 1396
  • تاریخ بازنگری: 20 فروردین 1397
  • تاریخ پذیرش: 18 اردیبهشت 1397

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