شیمی‌کانی و زمین دماسنجی اسفالریت و گالن در ذخیره فراگرمایی چنگوره، شمال غرب تاکستان-رهیافتی بر نوع کانی سازی

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشگاه تبریز

2 شرکت زمین فن آوران پویا

چکیده

ذخیره چنگوره در  25 کیلومتری شمال غرب تاکستان، در پهنه فلززائی ترشیاری طارم سفلی واقع است. تزریق نفوذی­های مونزوگرانیتی تا گرانودیوریتی به درون مجموعه آندزیتی- داسیتی ائوسن در منطقه سبب ایجاد دگرسانی گرمابی گسترده آرژیلی و سیلیسی و کانی­زائی رگه-رگچه­ای درون­زاد سولفیدی گالن، اسفالریت، پیریت و به ندرت کالکوپیریت و تتراهدریت- تنانتیت بهمراه کانی­های ثانویه برون­زاد سولفاتی (آنگلزیت)، کربناتی (سروزیت، مالاکیت، آزوریت)، سولفیدی (کوولیت) و اکسیدی (هماتیت،‌گوتیت) در پهنه اکسیدان شده است. در این پژوهش از زمین شیمی و زمین دماسنجی اسفالریت و گالن برای تعیین شرایط سولفیدشدگی، دمای سیال کانه­دار و نوع کانی­زایی استفاده شده است. حضور دو نسل گالن) رگچه­ای برشی شده الف دما بالا دربردارنده میانبارهای تتراهدریت و ب) دما- پایین همراه با اسفالریت کلوفرمی از ویژگی­های کانی­شناسی شاخص این ذخیره بشمار می­آید. براساس بررسی­های شیمی کانی نمونه­های اسفالریت چنگوره، متوسط تراکم عناصر Cd، Ga و Ge در شبکه اسفالریت به ترتیب 5870، 970 و
ppm 1380 است و میانگین نسبت­های Zn/Cd و Ga/Ge به ترتیب 4/165 و 39/1 بدست آمد. زمین دماسنج Ga/Ge در اسفالریت نیز دمای سیال کانه­دار را در گستره oC 220-170 نشان می­دهد. محاسبه log aS2 سیال گرمابی (5/11 - تا 5/13-) براساس درصد مولی FeS (80/0-33/0)، شرایط سولفیدشدگی متوسط را برای ذخیره گرمابی چنگوره پیشنهاد می­کند. با توجه به نتایج زمین دماسنجی Sb/Bi گالن و زمین­شیمی اسفالریت [مجموع گوگرد احیا ∑Sred نسبتاً پایین، تراکم متوسط Cd (ppm5870) و نسبت میانگین Zn/Cd (4/165)[ شرایط فیزیکوشیمیایی و ترمودینامیکی سیال کانه­دار در ذخیره چنگوره با ذخایر فراگرمایی دما-متوسط تا بالا همخوانی دارد.     

کلیدواژه‌ها

عنوان مقاله [English]

The Mineral chemistry and Geothermometry of Sphalerite and Galena in Changoreh epithermal deposit, NW of Takestan: implication to type of mineralization

نویسندگان [English]

  • Kamal Siahcheshm 1
  • Laila Alijani 1
  • Ali Asghar calagari 1
  • Behrouz Ahin 2
1 University of Tabriz
2 Zamin Fanavarn Poya Co
چکیده [English]

The study area is located about 25 km northwest of Takestan city, within Tarom-e-Sofla metallogenic belt. This area is covered by a widespread Eocene andesite to dasite volcanic rocks affected by Oligo-Miocene monzogranite to granodiorite igneous bodies which altered them to silicic, argillic zones as long as hypogene sulfide vein-veinlet mineralization (e.g. galena, sphalerite, pyrite, rare chalcopyrite and tetrahedrie- tennantite) occurred along with supergene minerals (e.g anglesite, cerussite, malachite, covellite and goethite in oxide zone). This study concentrated on geochemistry and geo-barometry of sphalerite and galena to evaluate sulfidation state, temperature and type of ore formation. During mineralography studies, two types of galena were recognized: 1) high temperature, brecciated veinlet type including tetrahedrite and, 2) low temperature coarse grained type along with colloform sphalerite. Based upon mineral chemistry of sphalerite, average concentration of Cd, Ga, Ge, Zn/Cd and Ga/Ge ratios were 5870, 970, 1380, 165.4 and 1.39, respectively. Ga/Ge ratios of sphalerites geothermometry indicate that the formation temperatures of sphalerite are between 170°C and 220°C. The amount of log aS2 hydrothermal fluid (-11.5 to -13.5), calculated from FeS content (0.33-0.80 mol%) in sphalerite, can be attributed to moderate sulfidation state for changoreh deposit. According to Sb/Bi in galena geo-thermometer, geochemistry of sphalerite (low ∑Sred activites, moderate Cd content (5870 ppm) and average Zn/Cd ratio (165.4), physico-chemical and thermodynamics of ore-bearing fluid in Changoreh is in accordance with moderate to high temperature epithermal deposits.

کلیدواژه‌ها [English]

  • Sphalerite
  • galena
  • Ga/Ge
  • Zn/Cd
  • geothermometrery
  • Changoreh
  • Takestan

مراجع

  1. [1] Zamin Fanavaran Poya., "Preliminary Report on prospecting and exploration of Changureh Pb deposit in the North of Takestan" (2004), 125 p.
  2. [1] Zamin Fanavaran Poya., "Preliminary Report on prospecting and exploration of Changureh Pb deposit in the North of Takestan" (2004), 125 p.
  3. [2] Scott S.D., "Chemical behaviour of sphalerite and arsenopyrite in hydrothermal and metamorphic environments", Mineral. Mag 47 (1983) 427-435. [DOI:10.1180/minmag.1983.047.345.03]
  4. [2] Scott S.D., "Chemical behaviour of sphalerite and arsenopyrite in hydrothermal and metamorphic environments", Mineral. Mag 47 (1983) 427-435. [DOI:10.1180/minmag.1983.047.345.03]
  5. [3] Deer F. R. S., Howie R. A., Zussman J., "An introduction to the rock forming minerals", Longman Scientific & Technical, Seventeenth impression (1378) 528p.
  6. [3] Deer F. R. S., Howie R. A., Zussman J., "An introduction to the rock forming minerals", Longman Scientific & Technical, Seventeenth impression (1378) 528p.
  7. [4] Boyle R. W., Jambor J. L., "The geochemistry and geothermometry of sphalerite in the lead-zinc-silver lodes of the Keno Hill-Galena Hill area, Yukon", Can. Mineral 7 (1963) 479–496.
  8. [4] Boyle R. W., Jambor J. L., "The geochemistry and geothermometry of sphalerite in the lead-zinc-silver lodes of the Keno Hill-Galena Hill area, Yukon", Can. Mineral 7 (1963) 479–496.
  9. [5] Viets J.G., Hopkins R.T., Miller B.M., "Variations in minor and trace elements in sphalerite from Mississippi Valley-Type deposits of the Ozark region: genetic implications", Economic Geology 87 (1992) 1897-1905. [DOI:10.2113/gsecongeo.87.7.1897]
  10. [5] Viets J.G., Hopkins R.T., Miller B.M., "Variations in minor and trace elements in sphalerite from Mississippi Valley-Type deposits of the Ozark region: genetic implications", Economic Geology 87 (1992) 1897-1905. [DOI:10.2113/gsecongeo.87.7.1897]
  11. [6] Ehtesham Z., "Lithogeochemical and Economic Geology Analysis of the Haft Sandogh district, North of Takestan, Qazvin Province" M.s. thesis on Economic Geology, University of Tabriz (2015), 90 p.
  12. [6] Ehtesham Z., "Lithogeochemical and Economic Geology Analysis of the Haft Sandogh district, North of Takestan, Qazvin Province" M.s. thesis on Economic Geology, University of Tabriz (2015), 90 p.
  13. [7] Nabavi M., "Preface to Iran Geology". Geological Survey & Mineral Explorations of Iran (GSI) (1976) 109 p.
  14. [7] Nabavi M., "Preface to Iran Geology". Geological Survey & Mineral Explorations of Iran (GSI) (1976) 109 p.
  15. [8] Aghanabati E., "Geology of Iran". Geological Survey & Mineral Explorations of Iran (GSI) (2004) 586 p.
  16. [8] Aghanabati E., "Geology of Iran". Geological Survey & Mineral Explorations of Iran (GSI) (2004) 586 p.
  17. [9] Nabi T., Mehrania S. R., Eslami H., "Study of lead mineralization in the Changureh region - Northwest of Takestan (Qazvin province)". The 19th Iranian Geological Society conference and the 9th National Geological Conference of Payame Noor University (2015).
  18. [9] Nabi T., Mehrania S. R., Eslami H., "Study of lead mineralization in the Changureh region - Northwest of Takestan (Qazvin province)". The 19th Iranian Geological Society conference and the 9th National Geological Conference of Payame Noor University (2015).
  19. [10] Azizi B., Makizadeh M.A., "The origin of hydrothermal alteration using stable isotopes in the Takestan region (lower Tarom zone)". Journal of Economic Geology, 1 (2009) 115-101.
  20. [10] Azizi B., Makizadeh M.A., "The origin of hydrothermal alteration using stable isotopes in the Takestan region (lower Tarom zone)". Journal of Economic Geology, 1 (2009) 115-101.
  21. [11] Alijani L., "Study of economic geology and genesis of Changureh polymetal with emphasis on Lead mineralization, Northwest of Takestan, Qazvin Province". M.s. thesis on Economic Geology, University of Tabriz (2015), 102 p.
  22. [11] Alijani L., "Study of economic geology and genesis of Changureh polymetal with emphasis on Lead mineralization, Northwest of Takestan, Qazvin Province". M.s. thesis on Economic Geology, University of Tabriz (2015), 102 p.
  23. [12] Costagliola P., Di Benedetto F., Benvenuti M., Bernardini G.P., Cipriani C., Lat‌tanzi P.F., Romanelli M.,"Chemical speciation of Ag in galena by EPR spectroscopy". American Mineralogist 88 (2003)1345–1350. [DOI:10.2138/am-2003-8-918]
  24. [12] Costagliola P., Di Benedetto F., Benvenuti M., Bernardini G.P., Cipriani C., Lat‌tanzi P.F., Romanelli M.,"Chemical speciation of Ag in galena by EPR spectroscopy". American Mineralogist 88 (2003)1345–1350. [DOI:10.2138/am-2003-8-918]
  25. [13] Renock D., Becker U., "A first principles study of coupled substitution in galena", Ore Geology Reviews 42 (2011) 71–83. [DOI:10.1016/j.oregeorev.2011.04.001]
  26. [13] Renock D., Becker U., "A first principles study of coupled substitution in galena", Ore Geology Reviews 42 (2011) 71–83. [DOI:10.1016/j.oregeorev.2011.04.001]
  27. [14] George L., Cook N. J., Ciobanu C. L., Wade B. P.,"Trace and minor elements in galena: A reconnaissance LA-ICP-MS study". Am. Mineral. 100 (2015) 548-569. [DOI:10.2138/am-2015-4862]
  28. [14] George L., Cook N. J., Ciobanu C. L., Wade B. P.,"Trace and minor elements in galena: A reconnaissance LA-ICP-MS study". Am. Mineral. 100 (2015) 548-569. [DOI:10.2138/am-2015-4862]
  29. [15] Amcoff O., "The solubility of silver and antimony in galena". Neues Jahrbuch für Mineralogie Monatshefte 6 (1976) 247-261.
  30. [15] Amcoff O., "The solubility of silver and antimony in galena". Neues Jahrbuch für Mineralogie Monatshefte 6 (1976) 247-261.
  31. [16] Atanassova R., Bonev I. K., "Two crystallographically different types of skeletal galena associated with colloform sphalerite", Mineral. Petrol 44 (2006) 1–18.
  32. [16] Atanassova R., Bonev I. K., "Two crystallographically different types of skeletal galena associated with colloform sphalerite", Mineral. Petrol 44 (2006) 1–18.
  33. [17] Barrie C. D., Boyce A. J., Boyle A., Williams P. C. K., Blake J. K., Wilkinson J. J., Lowther M., Mcdermott P., Prior D. J., "On the growth of colloform textures: a case study of sphalerite from the Galmoy ore body, Ireland", J. Geol. Soc. London 166 (2009) 563–582. [DOI:10.1144/0016-76492008-080]
  34. [17] Barrie C. D., Boyce A. J., Boyle A., Williams P. C. K., Blake J. K., Wilkinson J. J., Lowther M., Mcdermott P., Prior D. J., "On the growth of colloform textures: a case study of sphalerite from the Galmoy ore body, Ireland", J. Geol. Soc. London 166 (2009) 563–582. [DOI:10.1144/0016-76492008-080]
  35. [18] Zotov A.V., Kudri, A.V., Levin K.A., Shikina N.D., Varyash L.N., "Experimental studies of the solubility and complexing of selected ore elements (Au, Ag, Cu, Mo, As, Sb, Hg) in aqueous solutions", (1995) 95-132. In: Shmulovich K.I., Yardley B.W.D., Gonchar G.G., (eds.), Fluids in the Crust: Equilibrium and transport properties, Chapman and Hall, London, 323 p.
  36. [18] Zotov A.V., Kudri, A.V., Levin K.A., Shikina N.D., Varyash L.N., "Experimental studies of the solubility and complexing of selected ore elements (Au, Ag, Cu, Mo, As, Sb, Hg) in aqueous solutions", (1995) 95-132. In: Shmulovich K.I., Yardley B.W.D., Gonchar G.G., (eds.), Fluids in the Crust: Equilibrium and transport properties, Chapman and Hall, London, 323 p.
  37. [19] Acero P., Cama J., Ayor C., "Rate law for galena dissolution in acidic environment", Chem Geol 245 (2007), 219-229. [DOI:10.1016/j.chemgeo.2007.08.003]
  38. [19] Acero P., Cama J., Ayor C., "Rate law for galena dissolution in acidic environment", Chem Geol 245 (2007), 219-229. [DOI:10.1016/j.chemgeo.2007.08.003]
  39. [20] Szczerba M., Sawlowicz Z., "Remarks on the origin of cerussite in the Upper Silesian Zn-Pb deposits, Poland", Mineralogia 40 (2009) 53-64. [DOI:10.2478/v10002-009-0002-3]
  40. [20] Szczerba M., Sawlowicz Z., "Remarks on the origin of cerussite in the Upper Silesian Zn-Pb deposits, Poland", Mineralogia 40 (2009) 53-64. [DOI:10.2478/v10002-009-0002-3]
  41. [21] Forghani Tehrani G., Gheshlaghi A., "Mining wastes: specification, purification and environmental impacts", Shahrood University of Technology (2016), 600 p.
  42. [21] Forghani Tehrani G., Gheshlaghi A., "Mining wastes: specification, purification and environmental impacts", Shahrood University of Technology (2016), 600 p.
  43. [22] Whitney, D. L., & Evans, B. W. (2010). Abbreviations for names of rock-forming mineral. American mineralogist, 95(1), 185. [DOI:10.2138/am.2010.3371]
  44. [22] Whitney, D. L., & Evans, B. W. (2010). Abbreviations for names of rock-forming mineral. American mineralogist, 95(1), 185. [DOI:10.2138/am.2010.3371]
  45. [23] Moller P., " Development and application of the Ga/Ge-Geothermometer for sphalerite from sediment hosted deposits", In Germann K. (ed.), Geochemical aspects for Ore Formation in Recent and Fossil Sedimentary Environments", (1985) 15-30.
  46. [23] Moller P., " Development and application of the Ga/Ge-Geothermometer for sphalerite from sediment hosted deposits", In Germann K. (ed.), Geochemical aspects for Ore Formation in Recent and Fossil Sedimentary Environments", (1985) 15-30.
  47. [24] Geletii V.F., Chernishev L.V., Pastushkova T.M., "Distribution of cadmium and manganese between galena and sphalerite", Geologiia Rudnykh Mestoozhdenii 21 (1979) 66-75.
  48. [24] Geletii V.F., Chernishev L.V., Pastushkova T.M., "Distribution of cadmium and manganese between galena and sphalerite", Geologiia Rudnykh Mestoozhdenii 21 (1979) 66-75.
  49. [25] Wu Y., Hagni R.D., Paarlberg N., "Silver distribution in iron sulphides at the Buick and Brushy Creek Mines, Viburnum Trend, southeast Missouri", Society of Economic Geologists 4 (1996) 577-587.
  50. [25] Wu Y., Hagni R.D., Paarlberg N., "Silver distribution in iron sulphides at the Buick and Brushy Creek Mines, Viburnum Trend, southeast Missouri", Society of Economic Geologists 4 (1996) 577-587.
  51. [26] Cook N. J., Ciobanu C. L., Pring A., Skinner W., Shimizue M., Danyushevsky L., Saini-Eidukat B., Melcher F., "Trace and minor elements in sphalerite: A LA-ICPMS study" Geochim. Cosmochim. Acta 73 (2009) 4761–4791. [DOI:10.1016/j.gca.2009.05.045]
  52. [26] Cook N. J., Ciobanu C. L., Pring A., Skinner W., Shimizue M., Danyushevsky L., Saini-Eidukat B., Melcher F., "Trace and minor elements in sphalerite: A LA-ICPMS study" Geochim. Cosmochim. Acta 73 (2009) 4761–4791. [DOI:10.1016/j.gca.2009.05.045]
  53. [27] Ye L., Cook N. J., Ciobanu C. L., Liu Y. P., Zhang Q., Gao W., Yang Y. L., Danyushevsky L. V., "Trace and minor elements in sphalerite from base metal deposits in South China: a LA-ICPMS study" Ore Geol. Rev 39 (2011) 188–217. [DOI:10.1016/j.oregeorev.2011.03.001]
  54. [27] Ye L., Cook N. J., Ciobanu C. L., Liu Y. P., Zhang Q., Gao W., Yang Y. L., Danyushevsky L. V., "Trace and minor elements in sphalerite from base metal deposits in South China: a LA-ICPMS study" Ore Geol. Rev 39 (2011) 188–217. [DOI:10.1016/j.oregeorev.2011.03.001]
  55. [28] Marques de Sá, C., Noronha F., "Ga/Ge in Sphalerite Geothermometer - Aplication to Braçal Deposit", Comunicações Geológicas 99 (2012) 5-10.
  56. [28] Marques de Sá, C., Noronha F., "Ga/Ge in Sphalerite Geothermometer - Aplication to Braçal Deposit", Comunicações Geológicas 99 (2012) 5-10.
  57. [29] Song X., "Minor Elements and Ore Genesis of the Fankou Lead-Zinc deposit, China" Mineralium Deposita 19 (1984) 95-104.
  58. [29] Song X., "Minor Elements and Ore Genesis of the Fankou Lead-Zinc deposit, China" Mineralium Deposita 19 (1984) 95-104.
  59. [30] Monterio et al., 2005. Geology, "petrography, and mineral chemistry of the Vazante no sulfide and Ambrosia and Fagundes sulfide-rich carbonate-hosted Zn–(Pb) deposits, Minas Gerais", Brazil. Ore Geology Reviews, 34 p.
  60. [30] Monterio et al., 2005. Geology, "petrography, and mineral chemistry of the Vazante no sulfide and Ambrosia and Fagundes sulfide-rich carbonate-hosted Zn–(Pb) deposits, Minas Gerais", Brazil. Ore Geology Reviews, 34 p.
  61. [31] Barnes H. L., "Geochemistry of hydrothermal ore deposits" (1997) John Wiley Sons.
  62. [31] Barnes H. L., "Geochemistry of hydrothermal ore deposits" (1997) John Wiley Sons.
  63. [32] Lusk J., Calder B.O.E., "The composition of Sphalerite and associated sulfides in reactions of the Cu-Fe-Zn-S, Fe-Zn-S and Cu-Fe-S systems at 1 bar and temperatures between 250 and 535ºC", Chemical Geology 203 (2004) 319-345. [DOI:10.1016/j.chemgeo.2003.10.011]
  64. [32] Lusk J., Calder B.O.E., "The composition of Sphalerite and associated sulfides in reactions of the Cu-Fe-Zn-S, Fe-Zn-S and Cu-Fe-S systems at 1 bar and temperatures between 250 and 535ºC", Chemical Geology 203 (2004) 319-345. [DOI:10.1016/j.chemgeo.2003.10.011]
  65. [33] Scott S.D., Barnes H., "Sphalerite geothermometry and geobarometry". Econ Geol 66 (1971) 653-669. [DOI:10.2113/gsecongeo.66.4.653]
  66. [33] Scott S.D., Barnes H., "Sphalerite geothermometry and geobarometry". Econ Geol 66 (1971) 653-669. [DOI:10.2113/gsecongeo.66.4.653]
  67. [34] Einaudi, M.T., Hedenquist, J.W., and Inan E.E., 2003. Sulfidation State of Fluids in Active and Extinct Hydrothermal Systems: transitions from Porphyry to Epithermal Environments. Society of Economic Geologists, Special Publication 10, 285-313.
  68. [34] Einaudi, M.T., Hedenquist, J.W., and Inan E.E., 2003. Sulfidation State of Fluids in Active and Extinct Hydrothermal Systems: transitions from Porphyry to Epithermal Environments. Society of Economic Geologists, Special Publication 10, 285-313.
  69. [35] John D.A., Garside L.J., Wallace A.R., "Magmatic and tectonic setting of Late Cenozoic epithermal gold-silver deposits in northern Nevada, with an emphasis on the Pah Pah and Virginia Ranges and the Northern Nevada Rift" Geological Society of Nevada Special Publication 29 (1999) 64-158.
  70. [35] John D.A., Garside L.J., Wallace A.R., "Magmatic and tectonic setting of Late Cenozoic epithermal gold-silver deposits in northern Nevada, with an emphasis on the Pah Pah and Virginia Ranges and the Northern Nevada Rift" Geological Society of Nevada Special Publication 29 (1999) 64-158.
  71. [36] Wen H., Zhu C., Zhang Y., Cloquet C., Fan H., Fu S., "Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits", Sci. Rep., (2016), doi:10.1038/srep25273. [DOI:10.1038/srep25273]
  72. [36] Wen H., Zhu C., Zhang Y., Cloquet C., Fan H., Fu S., "Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits", Sci. Rep., (2016), doi:10.1038/srep25273. [DOI:10.1038/srep25273]
  73. [37] Schmitt A. D., Galer S. J. G., Abouchami W., "High-precision cadmium stable isotope measurements by double spike thermal ionization mass spectrometry". J. Anal. Atom. Spectrom 24 (2009) 1079–1088. [DOI:10.1039/b821576f]
  74. [37] Schmitt A. D., Galer S. J. G., Abouchami W., "High-precision cadmium stable isotope measurements by double spike thermal ionization mass spectrometry". J. Anal. Atom. Spectrom 24 (2009) 1079–1088. [DOI:10.1039/b821576f]
  75. [38] Sverjensky D. A., Shock E. L., Helgeson H. C., "Prediction of the thermodynamic properties of aqueous metal complexes to 1000 °C and 5 kbar" Geochim Cosmochim Acta 61 (1997) 1359–1412. [DOI:10.1016/S0016-7037(97)00009-4]
  76. [38] Sverjensky D. A., Shock E. L., Helgeson H. C., "Prediction of the thermodynamic properties of aqueous metal complexes to 1000 °C and 5 kbar" Geochim Cosmochim Acta 61 (1997) 1359–1412. [DOI:10.1016/S0016-7037(97)00009-4]
  77. [39] Bazarkina E. F., Pokrovski G. S., Zotov A. V., Hazemann, J.L., "Structure and stability of cadmium chloride complexes in hydrothermal fluids" Chem. Geol. 276 (2010) 1–17. [DOI:10.1016/j.chemgeo.2010.03.006]
  78. [39] Bazarkina E. F., Pokrovski G. S., Zotov A. V., Hazemann, J.L., "Structure and stability of cadmium chloride complexes in hydrothermal fluids" Chem. Geol. 276 (2010) 1–17. [DOI:10.1016/j.chemgeo.2010.03.006]
  79. [40] Tagirov B. R., Seward T. M., "Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite" Chem. Geol. 269 (2010) 301–311. [DOI:10.1016/j.chemgeo.2009.10.005]
  80. [40] Tagirov B. R., Seward T. M., "Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite" Chem. Geol. 269 (2010) 301–311. [DOI:10.1016/j.chemgeo.2009.10.005]

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  • تاریخ دریافت: 07 مرداد 1396
  • تاریخ بازنگری: 08 تیر 1396
  • تاریخ پذیرش: 27 مرداد 1396

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