سنتز ساختار بلوری هم بلور N'-(2- هیدروکسی-3متوکسی بنزیلیدن)-4- نیترو بنزوسولفونیل هیدرازید) و 1، 2- بیس(2- هیدروکسی-3متوکسی- بنزیلیدن هیدرازید)

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشگاه آزاد اسلامی واحد علوم و تحقیقات

2 دانشگاه آزاد اسلامی

3 دانشگاه آزاد اسلامی واحد اشکذر

4 انسیتو فیزیک ASCR،

چکیده

از واکنش پارا تولوئن سولفونیل هیدرازید و 2- هیدروکسی 3- متوکسی بنزآلدهید در شرایط تقطیر یک ترکیب هم­بلور N'-(2- هیدروکسی-3متوکسی بنزیلیدن)-4- نیترو بنزوسولفونیل هیدرازید) و 1، 2- بیس(2- هیدروکسی-3متوکسی- بنزیلیدن هیدرازید) (1) تهیه شد. وجود پیوندهای هیدورژنی به نسبت قوی در ترکیب 1 بر اثر اتصال اتم­های اکسیژن یک مولکول 1، 2- بیس (2-­هیدروکسی-3­–­ متوکسی بنزیلیدن هیدرازید) به گروه NH از N'-(2- هیدروکسی-3متوکسی بنزیلیدن)-4- نیترو بنزوسولفونیل هیدرازید) می­تواند باعث پایداری ساختار هم بلور باشد. ترکیب 1 با استفاده از روش­های طیف­سنجی فروسرخ (IR)، تشدید مغناطیسی هسته (­NMR)، تجزیه­ی عنصری و پراش پرتوی X (X-ray) شناسایی شد. اطلاعات بلورشناسی برای این ترکیب در دمایK 95 جمع­ آوری شد. ترکیب در سیستم بلوری تک­میل، گروه فضایی P < /span>21/n و با چهار مولکول در یاخته یکه تبلور یافته است. پارامترهای شبکه­ای آن عبارت از ˚(3) 56/95 = β، Å(1)398/17 = c، Å (1)207/19 = b، Å (1)677/6= a و مقدار نهاییR  برای 4047 بازتابش­های مستقل برابر 037/0 هستند.    

کلیدواژه‌ها

عنوان مقاله [English]

Crystal Structure of N'-(2-hydroxy-3-methoxy benzylidene)-4-nitro benzenesulfonylhydrazide and 1,2-bis(2-hydroxy-3-methoxy-benzylidenehydrazine) as a co-crystalline compound

نویسندگان [English]

  • Tahriri 1
  • Yousefi 2
  • Tabatabaee 1
  • Mehrani 1
  • Dehghani Ashkezari 3
  • Dusek 4
1
2
3
4
چکیده [English]

The reaction of 2-hydroxy-3-methoxybenzaldehyde with 4-nitrosulfonylhydrazide under refluxing led to co-crystalline compound contains N'-(2-hydroxy-3-methoxy benzylidene)-4-nitro benzenesulfonylhydrazide (a sulfonamide-Schiff base compound) and 1,2-bis (2-hydroxy-3-methoxy-benzylidenehydrazine) (I). A medium strong hydrogen bonds in 1 links the oxygen atoms of one molecule of 1,2-bis(2-hydroxy-3-methoxy-benzylidenehydrazine) to the NH group of the N'-(2-hydroxy-3-methoxy benzylidene)-4-nitrobenzenesulfonylhydrazide and is responsible for establishing of co-crystals. Compound 1 was characterized by NMR and IR spectroscopy, elemental analysis and single crystal X-ray diffraction method. Crystallographic data for 1 was collected at 95 K.  The synthesized compound has been crystallized in monoclinic system with P21/n space group and a = 6.6771(2) Å, b = 19.2072(6) Å, c = 17.3980(1) Å, β = 95.56(3)º cell parameters. The final R value is 0.037 for 07 independent reflections.

کلیدواژه‌ها [English]

  • 4-nitrosulfonyl hydrazide
  • Schiff base
  • cocrystal
  • crystal structure

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مجله بلورشناسی و کانی شناسی ایران
دوره 26، شماره 1 - شماره پیاپی 69
فروردین 1397
صفحه 245-250

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سابقه مقاله

  • تاریخ دریافت: 20 خرداد 1396
  • تاریخ بازنگری: 08 تیر 1396
  • تاریخ پذیرش: 23 مرداد 1396

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