Preparation aod Molecular Structure of
l,3-Dipbenyltriazene Copper (I) Complex
Abstract
I ,3 -Diphenyltriazene (HDPT) reacts with NaH in THF and
generates the sodium salt (NaDPT). Further reaction of
[Cu(fMEDA)h[CuCld with one equivalent of this ligand in THF leads
to the formation of a dimeric Cu (I) complex, (Cu(DPT)h. The
moleculat structure has been determine(! by using single -crystal X-ray
diffraction method. The orange complex crystallizes in monoclinic space
group C2Jc with four molecules per unit cell. The unit cell dimensions
are a=26.184(12), b=5.564(2), and c= 15.695(5)A WilhP= 116.51(3)".
The final R value is 0.054 for 2050 reflections measured. Cootdination
number around each copper is two (nearly linear). The Cu-Cu distance
is 2.447(2)A.
(2025). Preparation aod Molecular Structure of
l,3-Dipbenyltriazene Copper (I) Complex. Iranian Journal of Crystallography and Mineralogy, 2(1), 3-12.
MLA
. "Preparation aod Molecular Structure of
l,3-Dipbenyltriazene Copper (I) Complex", Iranian Journal of Crystallography and Mineralogy, 2, 1, 2025, 3-12.
HARVARD
(2025). 'Preparation aod Molecular Structure of
l,3-Dipbenyltriazene Copper (I) Complex', Iranian Journal of Crystallography and Mineralogy, 2(1), pp. 3-12.
VANCOUVER
Preparation aod Molecular Structure of
l,3-Dipbenyltriazene Copper (I) Complex. Iranian Journal of Crystallography and Mineralogy, 2025; 2(1): 3-12.
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