نوع مقاله : مقاله پژوهشی
نویسندگان
دانشگاه فردوسی مشهد. دانشکده علوم
چکیده
کلیدواژهها
عنوان مقاله [English]
نویسندگان [English]
N-(5,5-dimethyl-2-oxo-1,3,2-diazaphosphorinan-2-yl)-4-chlorophenoxy phosphorylamide crystallizes in the monoclinic space group P21/c, with one molecule in the asymmetric unit. The crystal structure of the compound was determined at 95 K using X-ray diffraction with CuKα radiation and solved by the SHELXT program. The crystal parameters are a = 11.4455(1) Å, b = 9.4481(1) Å, and c = 12.5377(1) Å, with Z = 4. The synperiplanar (sp) orientation of the PONH fragment is suitable for the formation of an R22(8)hydrogen-bond motif between two adjacent molecules. The three-dimensional assembly includes H···O, H···H, H···Cl, and H···π contacts. Hirshfeld surface analysis and energy frameworks were employed to illustrate intermolecular interactions and calculate interaction energies between molecular pairs.
کلیدواژهها [English]
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